9-tert-butyl 2-methyl 9-azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylate

Base Information

Chemical Name:9-tert-butyl 2-methyl 9-azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylate
CAS No.:125736-10-9
Molecular Formula:C₁₅H₂₃NO₄
Molecular Weight:281.352
Hs Code.:
Mol file:125736-10-9.mol

Synonyms:9-Azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylicacid, 9-(1,1-dimethylethyl) 2-methyl ester, (?à)-

Suppliers and Price of 9-tert-butyl 2-methyl 9-azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 9-tert-butyl 2-methyl 9-azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylate

Chemical Property:

Vapor Pressure:1.56E-05mmHg at 25°C
Boiling Point:365.6°Cat760mmHg
Flash Point:174.9°C
Density:1.135g/cm³

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 9-tert-butyl 2-methyl 9-azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylate

There total 2 articles about 9-tert-butyl 2-methyl 9-azabicyclo[4.2.1]non-2-ene-2,9-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 125736-08-5,125736-09-6
2-Phenylselanyl-9-aza-bicyclo[4.2.1]nonane-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester

: 125736-10-9
9-Aza-bicyclo[4.2.1]non-2-ene-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; a) 0 deg C, 45 min, b) r.t., 30 min;
DOI:10.1021/jo00296a050

Reference yield:

: 125736-06-3,125736-07-4,129099-02-1,129170-27-0
9-Aza-bicyclo[4.2.1]nonane-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester

: 125736-10-9
9-Aza-bicyclo[4.2.1]non-2-ene-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) nBuLi, iPr₂NH, 2) diphenyl diselenide

2: 74 percent / MCPBA / CH₂Cl₂ / a) 0 deg C, 45 min, b) r.t., 30 min

With n-butyllithium; diphenyl diselenide; diisopropylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo00296a050