5-Bromo-1,3-dichloro-2-iodobenzene

Base Information

• Chemical Name: 5-Bromo-1,3-dichloro-2-iodobenzene
• CAS No.: 62720-30-3
• Molecular Formula: C6H2BrCl2I
• Molecular Weight: 351.796
• Hs Code.: 2903999090
• European Community (EC) Number: 636-372-1
• DSSTox Substance ID: DTXSID70404415
• Nikkaji Number: J2.057.969B
• Wikidata: Q82208603
• Mol file: 62720-30-3.mol

Synonyms:5-bromo-1,3-dichloro-2-iodobenzene;62720-30-3;4-Bromo-2,6-dichloroiodobenzene;Benzene, 5-bromo-1,3-dichloro-2-iodo-;SCHEMBL5354779;2,6-dichloro-4-bromoiodobenzene;DTXSID70404415;ZKNRQIMIXPBAGW-UHFFFAOYSA-N;MFCD00155014;AKOS009319830;BS-42432;CS-0195320;E89418;A868382

Chemical Property of 5-Bromo-1,3-dichloro-2-iodobenzene

Chemical Property:

• Melting Point: 67.8-68.7 °C
• Boiling Point: 314.2±37.0 °C(Predicted)
• PSA: 0.00000
• Density: 2.320±0.06 g/cm3(Predicted)
• LogP: 4.36050
• Storage Temp.: 2-8°C(protect from light)
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 349.77617
• Heavy Atom Count: 10
• Complexity: 110

Purity/Quality:

98.5% ^*data from raw suppliers

5-Bromo-1,3-dichloro-2-iodobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=C(C=C(C(=C1Cl)I)Cl)Br

Technology Process of 5-Bromo-1,3-dichloro-2-iodobenzene

There total 3 articles about 5-Bromo-1,3-dichloro-2-iodobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromo-2,6-dichloroaniline (697-88-1) → dichloro(1,1'-dimethylsilylenebis{2-ethyl-4-(4-trimethylsilyl-3,5-dichlorophenyl)-4H-azulenyl})hafnium + 5-bromo-1,3-dichloro-2-iodobenzene (62720-30-3)

Guidance literature:

With potassium iodide; sulfuric acid; sodium thiosulfate; sodium nitrite; In ice-water;

Reference yield:

4-bromo-2,6-dichloroaniline (697-88-1) → 5-bromo-1,3-dichloro-2-iodobenzene (62720-30-3)

Guidance literature:

With sulfuric acid; acetic acid; potassium iodide; sodium nitrite; Yield given. Multistep reaction; 1.)0-5 deg C; 2.)heated;

Reference yield:

2,6-Dichloroaniline (608-31-1) → 5-bromo-1,3-dichloro-2-iodobenzene (62720-30-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: bromine; hydrochloric acid

2.1: sodium nitrite; HCl / H₂O

2.2: potassium iodide / H₂O

With hydrogenchloride; bromine; sodium nitrite; In water;

DOI:10.1016/j.tet.2004.09.020

upstream raw materials:

4-bromo-2,6-dichloroaniline

2,6-Dichloroaniline

Downstream raw materials:

1-bromo-3,5-dichlorobenzene

3,5-dichloro-4-trimethylsilyl-bromobenzene

Refernces

• 1、 -. "Catalyst component for olefin polymerization, catalyst for alpha-olefin polymerization and process for the production of alpha-olefin polymer". . . Retrieved 2008/06/13.