Bis(4-chlorophenoxy)(dimethyl)silane

Base Information

• Chemical Name: Bis(4-chlorophenoxy)(dimethyl)silane
• CAS No.: 18414-46-5
• Molecular Formula: C14H14Cl2O2Si
• Molecular Weight: 313.2513
• NSC Number: 35354
• DSSTox Substance ID: DTXSID50284070
• Wikidata: Q82018878

Synonyms:18414-46-5;bis(4-chlorophenoxy)(dimethyl)silane;NSC35354;DTXSID50284070;NSC-35354

Chemical Property of Bis(4-chlorophenoxy)(dimethyl)silane

Chemical Property:

• Vapor Pressure: 0.000121mmHg at 25°C
• Boiling Point: 345.6°C at 760 mmHg
• Flash Point: 135.5°C
• Density: 1.214g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 312.0140116
• Heavy Atom Count: 19
• Complexity: 247

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(OC1=CC=C(C=C1)Cl)OC2=CC=C(C=C2)Cl

Technology Process of Bis(4-chlorophenoxy)(dimethyl)silane

There total 3 articles about Bis(4-chlorophenoxy)(dimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethoxy dimethylsilane (78-62-6) + 4-chloro-phenol (106-48-9,82344-39-6) → Dimethyl-bis-<4-chlorphenoxy>-silan (18414-46-5) + me2Si(Oet)(Oph-4-Cl) (17903-54-7)

Guidance literature:

DOI:10.1021/ja01124a039

Reference yield:

4-chloro-phenol (106-48-9,82344-39-6) + dimethylsilicon dichloride (75-78-5,30107-43-8) → Dimethyl-bis-<4-chlorphenoxy>-silan (18414-46-5)

Guidance literature:

heating of (CH3)2SiCl2 and ClC6H4OH at about 150°C;;

Reference yield:

→ Dimethyl-bis-<4-chlorphenoxy>-silan (18414-46-5)

Guidance literature:

p-Chlorphenol, (CH3)2SiCl2 / (C2H5)3N;

upstream raw materials:

diethoxy dimethylsilane

4-chloro-phenol

dimethylsilicon dichloride

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