Oxiranemethanol, 3,3-dimethyl-, benzoate

Base Information

Chemical Name:Oxiranemethanol, 3,3-dimethyl-, benzoate
CAS No.:62894-01-3
Molecular Formula:C12H14O3
Molecular Weight:206.241
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Oxiranemethanol, 3,3-dimethyl-, benzoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of Oxiranemethanol, 3,3-dimethyl-, benzoate

There total 5 articles about Oxiranemethanol, 3,3-dimethyl-, benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 5205-11-8
3-methyl-2-butenyl benzoate

: 62894-01-3
(3,3-dimethyloxiran-2-yl)methyl benzoate

Guidance literature:: With Ni(dmp)2; oxygen; isovaleraldehyde; In 1,2-dichloro-ethane; for 24h; under 760 Torr; Ambient temperature;
DOI:10.1246/bcsj.64.2109

Reference yield: 62.0%

: 5205-11-8
3-methyl-2-butenyl benzoate

: 142083-65-6
3-hydroxy-3-methyl-2-oxobutyl benzoate

: 62894-01-3
(3,3-dimethyloxiran-2-yl)methyl benzoate

Guidance literature:: With oxygen; isobutyraldehyde; osmium(VIII) oxide; Ni(mac)2; In acetone; for 14h; Product distribution; Ambient temperature; other catalysts, without aldehyde, without O₂;
DOI:10.1246/cl.1991.1499

Reference yield:

: 556-82-1
3-methyl-2-buten-1-ol

: 62894-01-3
(3,3-dimethyloxiran-2-yl)methyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: titanium(IV)isopropoxide; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate / dichloromethane / 1.25 h / -25 - -20 °C / Molecular sieve; Inert atmosphere

1.2: 0.17 h / -30 °C / Molecular sieve; Inert atmosphere

1.3: 1.25 h / -30 - -10 °C / Molecular sieve; Inert atmosphere

2.1: triethylamine / dichloromethane / 0.25 h / Inert atmosphere

With tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; titanium(IV)isopropoxide; triethylamine; In dichloromethane; 1.1: |Sharpless Asymmetric Epoxidation / 1.2: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/acs.orglett.5b01121