Gona-1,3,5,7,9,15-hexaen-12-one, (13xi,14xi)-

Base Information

• Chemical Name: Gona-1,3,5,7,9,15-hexaen-12-one, (13xi,14xi)-
• CAS No.: 80299-44-1
• Molecular Formula: C17H14O
• Molecular Weight: 234.2925
• Mol file: 80299-44-1.mol

Synonyms:Gona-1,3,5,7,9,15-hexaen-12-one,(13xi,14xi);

Chemical Property of Gona-1,3,5,7,9,15-hexaen-12-one, (13xi,14xi)-

Chemical Property:

• Vapor Pressure: 1.7E-07mmHg at 25°C
• Boiling Point: 427°Cat760mmHg
• Flash Point: 190.7°C
• PSA: 17.07000
• Density: 1.205g/cm³
• LogP: 3.62470

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Gona-1,3,5,7,9,15-hexaen-12-one, (13xi,14xi)-

There total 3 articles about Gona-1,3,5,7,9,15-hexaen-12-one, (13xi,14xi)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

7-(1-naphthyl)-bicyclo<3.2.0>hept-2-en-6-one (67279-05-4) → (13S,14R)-11,13,14,17-Tetrahydro-cyclopenta[a]phenanthren-12-one (67279-07-6,80299-44-1)

Guidance literature:

methanesulfonic acid; In diethyl ether; for 1h; Ambient temperature;

Reference yield:

naphthalen-1-yl-acetyl chloride (5121-00-6) → (13S,14R)-11,13,14,17-Tetrahydro-cyclopenta[a]phenanthren-12-one (67279-07-6,80299-44-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 2.) triethylamine / 1.) benzene, reflux; 2.) benzene, 30 min, RT

2: 85 percent / methanesulphonic acid / diethyl ether / 1 h / Ambient temperature

With triethylamine; methanesulfonic acid; In diethyl ether;

Reference yield:

naphth-1-yl acetic acid (86-87-3) → (13S,14R)-11,13,14,17-Tetrahydro-cyclopenta[a]phenanthren-12-one (67279-07-6,80299-44-1)

Guidance literature:

Multi-step reaction with 3 steps

1: thionyl chloride / Ambient temperature

2: 2.) triethylamine / 1.) benzene, reflux; 2.) benzene, 30 min, RT

3: 85 percent / methanesulphonic acid / diethyl ether / 1 h / Ambient temperature

With thionyl chloride; triethylamine; methanesulfonic acid; In diethyl ether;

upstream raw materials:

7-(1-naphthyl)-bicyclo<3.2.0>hept-2-en-6-one

naphthalen-1-yl-acetyl chloride

naphth-1-yl acetic acid

Downstream raw materials:

3H-Cyclopentaphenanthrene

(13S,14R)-12,13,14,17-Tetrahydro-11H-cyclopenta[a]phenanthren-12-ol

Refernces