Technology Process of N-(Dimethylboranyl)-1,1,1-trimethyl-N-(trimethylstannyl)stannanamine
There total 1 articles about N-(Dimethylboranyl)-1,1,1-trimethyl-N-(trimethylstannyl)stannanamine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
dichloromethane;
N2 atmosphere, addn. of soln. of borane to soln. of stannyl compound at -78 to -60°C (2 h), warming to room temp., stirring (room temp., 1 h); spectroscopic yield 100%, not isolated;
- Guidance literature:
-
In
dichloromethane;
a soln. of MeBBr2 was added dropwise to a soln. of the amine at-78°C with stirring; after formation of the diborylamine, as verified by 11B NMR, the soln. was slowly warmed up to room temp.; all reactions under N2 with exclusion of moisture;; after evapn. of all volatiles at 100 Torr and fractionated distn. (residue is a highly viscous liq.), the borazine crystd. in the recipient; elem. anal.;;
