Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl-

Base Information

Chemical Name:Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl-
CAS No.:63922-70-3
Molecular Formula:C24H29PSi
Molecular Weight:376.554
Hs Code.:
DSSTox Substance ID:DTXSID40447470

Synonyms:Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl-;63922-70-3;DTXSID40447470

Suppliers and Price of Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:5
Exact Mass:376.17761446
Heavy Atom Count:26
Complexity:431

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)C[Si](C)(C)C

Technology Process of Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl-

There total 1 articles about Phosphorane, [1-methyl-2-(trimethylsilyl)ethylidene]triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4206-67-1
iodo(trimethylsilyl)methane

: 1530-32-1
ethyltriphenylphosphonium bromide

: 63922-70-3
1-Methyl-2-trimethylsilylethylidenetriphenylphosphorane

Guidance literature:: Multistep reaction;
DOI:10.1021/ja00019a038

Reference yield: 50.0%

: 148111-10-8
4-(3-Oxo-cyclohex-1-enyl)-pentanal

: 63922-70-3
1-Methyl-2-trimethylsilylethylidenetriphenylphosphorane

: 127311-64-2
3-((E)-1,5-Dimethyl-6-trimethylsilanyl-hex-4-enyl)-cyclohex-2-enone

Guidance literature:: In tetrahydrofuran;
DOI:10.1021/jo00300a003

Reference yield:

: 63922-70-3
1-Methyl-2-trimethylsilylethylidenetriphenylphosphorane

: 97551-21-8
4-<3-methyl-4-(trimethylsilyl)-2-butenyl>-4,5-dimethyl-3-vinyl-2-cyclohexenone

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, hexane, from -78 deg C to 0 deg C, 1 h, 2.) THF, hexane, from -78 deg C to RT, 3.5 h

2: tetrahydrofuran / 0.5 h / 0 °C

3: 1 N aq. HCl / tetrahydrofuran / 0.5 h / Ambient temperature

With hydrogenchloride; n-butyllithium; In tetrahydrofuran;
DOI:10.1021/jo00219a034