Silane, trimethyl-2-nonenyl-, (E)-

Base Information

Chemical Name:Silane, trimethyl-2-nonenyl-, (E)-
CAS No.:63922-74-7
Molecular Formula:C12H26Si
Molecular Weight:198.424
Hs Code.:

Synonyms:1-trimethylsilyl-2-nonene;(E)-trimethyl(non-2-enyl)silane;(E)-1-trimethylsilyl-2-nonene;(E)-2-nonenyltrimethylsilane;(E)-1-(Trimethylsilyl)non-2-ene;(E)-1-(nonenyl)SiMe3;

Suppliers and Price of Silane, trimethyl-2-nonenyl-, (E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of Silane, trimethyl-2-nonenyl-, (E)-

Chemical Property:

PSA：0.00000
LogP:4.85120

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of Silane, trimethyl-2-nonenyl-, (E)-

There total 2 articles about Silane, trimethyl-2-nonenyl-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.5%

: (η5-C5H5)2ZrCl(octenyl-1-E)

: 63830-85-3
chloro(trimethylsilyl)methyl lithium

: 75-76-3
tetramethylsilane

: 63922-74-7
(E)-1-(Trimethylsilyl)-2-nonene

: 120059-89-4
(E)-1-trimethylsilyl-1-nonene

: 7,9-hexadecadiene

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; mixing of Zr-complex with Li-salt in THF (molar ratio 1:1, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
DOI:10.1021/ja00190a067

Reference yield: 22.5%

: (η5-C5H5)2Zr(octenyl-1-E)2

: 63830-85-3
chloro(trimethylsilyl)methyl lithium

: 75-76-3
tetramethylsilane

: 63922-74-7
(E)-1-(Trimethylsilyl)-2-nonene

: 120059-89-4
(E)-1-trimethylsilyl-1-nonene

: 7,9-hexadecadiene

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; mixing of Zr-complex with Li-salt in THF (molar ratio 1:1, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
DOI:10.1021/ja00190a067

Reference yield:

: 63922-74-7
(E)-1-(Trimethylsilyl)-2-nonene

: 21964-44-3,79605-61-1
non-1-en-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / Na₂EDTA; di(chloromethyl)dioxirane; Bu₄NHSO₄ / acetonitrile

2: 65 percent / KN(TMS)2; 18-Crown-6 / tetrahydrofuran / -78 °C

With 18-crown-6 ether; di(chloromethyl)dioxirane; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; potassium hexamethylsilazane; In tetrahydrofuran; acetonitrile;
DOI:10.1002/hc.10036