Trimethylsilyl sulfanylacetate

Base Information

• Chemical Name: Trimethylsilyl sulfanylacetate
• CAS No.: 6398-65-8
• Molecular Formula: C5H12O2SSi
• Molecular Weight: 164.301
• DSSTox Substance ID: DTXSID20575467
• Wikidata: Q82464822
• Mol file: 6398-65-8.mol

Synonyms:Trimethylsilyl sulfanylacetate;6398-65-8;DTXSID20575467;thioglycolic acid trimethylsilyl ester

Chemical Property of Trimethylsilyl sulfanylacetate

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 164.03272733
• Heavy Atom Count: 9
• Complexity: 108

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OC(=O)CS

Technology Process of Trimethylsilyl sulfanylacetate

There total 1 articles about Trimethylsilyl sulfanylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

mercaptoacetic acid (68-11-1) + trimethylsilylacetylene (1066-54-2) → 2-methyl-1,3-oxathiolan-5-one (37510-18-2) + (ethylenedithio)diacetic acid (7244-02-2) + Thioglykolsaeure-trimethylsilylester (6398-65-8)

Guidance literature:

for 2h; Irradiation;

Reference yield: 21.0%

Thioglykolsaeure-trimethylsilylester (6398-65-8) + acetone phenylhydrazone (103-02-6) → 2,2-dimethyl-3-phenylamino-1,3-thiazolidin-4-one

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; for 10h; Ambient temperature;

DOI:10.3987/COM-95-7151

upstream raw materials:

mercaptoacetic acid

trimethylsilylacetylene