Methyl 2-benzylidenebutanoate

Base Information

Chemical Name:Methyl 2-benzylidenebutanoate
CAS No.:64262-65-3
Molecular Formula:C12H14O2
Molecular Weight:190.242
Hs Code.:
DSSTox Substance ID:DTXSID50707178

Synonyms:Methyl 2-benzylidenebutanoate;64262-65-3;SCHEMBL5284839;DTXSID50707178

Suppliers and Price of Methyl 2-benzylidenebutanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Methyl 2-benzylidenebutanoate

Chemical Property:

XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:190.099379685
Heavy Atom Count:14
Complexity:212

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(=CC1=CC=CC=C1)C(=O)OC

Technology Process of Methyl 2-benzylidenebutanoate

There total 4 articles about Methyl 2-benzylidenebutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 79868-63-6
2-(α-hydroxy-benzyl)-butyric acid methyl ester

: 64262-65-3
methyl 2-ethyl-3-phenylpropenoate

Guidance literature:: With dmap; acetic anhydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 130 ℃; stereoselective reaction;
DOI:10.1248/cpb.c18-00666

Reference yield: 49.0%

: 75-24-1
trimethylaluminum

: 174858-25-4
methyl (2Z)-2-(chloromethyl)-3-phenylprop-2-enoate

: 64262-65-3
methyl 2-ethyl-3-phenylpropenoate

Guidance literature:: trimethylaluminum; methyl (2Z)-2-(chloromethyl)-3-phenylprop-2-enoate; With bis(acetylacetonate)nickel(II); In tetrahydrofuran; n-heptane; at 10 ℃; for 24h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; n-heptane; water; regioselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.200801029

Reference yield:

: 75-24-1
trimethylaluminum

: 174858-25-4
methyl (2Z)-2-(chloromethyl)-3-phenylprop-2-enoate

: (R)-3-phenyl-2-methylene-butyric acid methyl ester

: (S)-3-phenyl-2-methylene-butyric acid methyl ester

: 64262-65-3
methyl 2-ethyl-3-phenylpropenoate

Guidance literature:: trimethylaluminum; methyl (2Z)-2-(chloromethyl)-3-phenylprop-2-enoate; With bis(acetylacetonate)nickel(II); C₂₈H₂₁FeO₂P; In tetrahydrofuran; at 10 ℃; for 72h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; water; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.200801029