Iridium, dichloro(3,3-dimethyl-1-oxobutyl)bis(triphenylphosphine)-

Base Information

Chemical Name:Iridium, dichloro(3,3-dimethyl-1-oxobutyl)bis(triphenylphosphine)-
CAS No.:651042-94-3
Molecular Formula:C₄₂H₄₁Cl₂IrOP₂
Molecular Weight:886.86
Hs Code.:

Synonyms:

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Chemical Property of Iridium, dichloro(3,3-dimethyl-1-oxobutyl)bis(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
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MSDS Files:: SDS file from LookChem

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Technology Process of Iridium, dichloro(3,3-dimethyl-1-oxobutyl)bis(triphenylphosphine)-

There total 4 articles about Iridium, dichloro(3,3-dimethyl-1-oxobutyl)bis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

: 917-92-0
3,3-Dimethylbut-1-yne

: 7732-18-5
water

: 651042-94-3
[IrCl2(triphenylphosphine)2(η1-C(O)CH2C(CH3)3)]

Guidance literature:: In dichloromethane; byproducts: H2; (Ar); addn. of excess of alkyne to a soln. of iridium complex in CH2Cl2,stirring at room temp. for 40 h; evapn., trituration with ethanol, filtration, recrystn. (CH2Cl2/ethanol); elem. anal.;
DOI:10.1039/b303635a

Reference yield: 38.0%

: 917-92-0
3,3-Dimethylbut-1-yne

: 881381-24-4
[IrHCl₂(triphenylphosphine)2(imidazole)]

: 7732-18-5
water

: 651042-94-3
[IrCl2(triphenylphosphine)2(η1-C(O)CH2C(CH3)3)]

Guidance literature:: With CF₃SO₃H; In dichloromethane; under Ar or N2 atm. using Schlenk techniques; equimolar amt. of CF3SO3H added to soln. of Ir complex in CH2Cl2 cooled to -196°C; mixt. warmed to room temp.; stirred for 1 h; excess of Me3CCCH added; mixt. stirred at room temp. for 24 h; solvent removed (vac.); solid treated (EtOH); solid slowly filtered; crystd. from CH2Cl2 and EtOH; elem. anal.;
DOI:10.1016/j.jorganchem.2005.11.004

Reference yield:

: 917-92-0
3,3-Dimethylbut-1-yne

: 881381-20-0
[IrHCl₂(triphenylphosphine)2(pyrazole)]

: 7732-18-5
water

: 651042-94-3
[IrCl2(triphenylphosphine)2(η1-C(O)CH2C(CH3)3)]

Guidance literature:: With HBF₄*(C₂H₅)2O; In not given; equimolar amt. of HBF4*Et2O added to Ir complex; excess of alkyne added;
DOI:10.1016/j.jorganchem.2005.11.004