(3-CHLORO-2-METHYLPHENYL)HYDRAZINE HYDROCHLORIDE

Base Information

• Chemical Name: (3-CHLORO-2-METHYLPHENYL)HYDRAZINE HYDROCHLORIDE
• CAS No.: 65208-12-0
• Molecular Formula: C7H9ClN2.ClH
• Molecular Weight: 193.07400
• Hs Code.: 2928000090
• Mol file: 65208-12-0.mol

Synonyms:3-chloro-2-tolyl-hydrazine hydrochloride;

Chemical Property of (3-CHLORO-2-METHYLPHENYL)HYDRAZINE HYDROCHLORIDE

Chemical Property:

• PSA: 38.05000
• LogP: 3.50930

Purity/Quality:

98%min ^*data from raw suppliers

(3-Chloro-2-methylphenyl)hydrazineHydrochloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,T
• Statements: 25
• Safety Statements: 45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (3-CHLORO-2-METHYLPHENYL)HYDRAZINE HYDROCHLORIDE

There total 2 articles about (3-CHLORO-2-METHYLPHENYL)HYDRAZINE HYDROCHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-chloro-2-methylbenzenamine (87-60-5) → (3-chloro-2-methyl-phenyl)-hydrazine; hydrochloride (65208-12-0)

Guidance literature:

3-chloro-2-methylbenzenamine; With hydrogenchloride; In water; at 0 ℃;

With sodium nitrite; In water; at 0 ℃; for 0.5h;

With hydrogenchloride; tin(II) chloride hydrate; In water; at 0 ℃; for 4h;

DOI:10.1016/j.ejmech.2018.05.058

Reference yield:

→ (3-chloro-2-methyl-phenyl)-hydrazine; hydrochloride (65208-12-0)

Guidance literature:

With hydrogenchloride; tin(ll) chloride;

DOI:10.1021/jo01110a004 DOI:10.1021/ja01603a040

Reference yield: 91.0%

(3-chloro-2-methyl-phenyl)-hydrazine; hydrochloride (65208-12-0) + (4-nitrophenyl)ethanone (100-19-6) → N-(3-Chloro-2-methyl-phenyl)-N'-[1-(4-nitro-phenyl)-eth-(E)-ylidene]-hydrazine (77635-74-6)

Guidance literature:

In ethanol; for 1h; Heating;

DOI:10.1021/jm00137a011

upstream raw materials:

3-chloro-2-methylbenzenamine

Downstream raw materials:

N-(3-Chloro-2-methyl-phenyl)-N'-[2,2,2-trifluoro-1-phenyl-eth-(Z)-ylidene]-hydrazine

N-(3-Chloro-2-methyl-phenyl)-N'-[1-(2-trifluoromethyl-phenyl)-eth-(E)-ylidene]-hydrazine

N-(3-Chloro-2-methyl-phenyl)-N'-[1-(4-nitro-phenyl)-eth-(E)-ylidene]-hydrazine

N-(3-Chloro-2-methyl-phenyl)-N'-[1-(3-nitro-phenyl)-eth-(E)-ylidene]-hydrazine

Refernces