Gold, (pentafluorophenyl)(piperidine)-

Base Information

• Chemical Name: Gold, (pentafluorophenyl)(piperidine)-
• CAS No.: 653599-29-2
• Molecular Formula: C₁₁H₁₁AuF₅N
• Molecular Weight: 449.174
• Mol file: 653599-29-2.mol

Synonyms:

Chemical Property of Gold, (pentafluorophenyl)(piperidine)-

Chemical Property:

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Gold, (pentafluorophenyl)(piperidine)-

There total 3 articles about Gold, (pentafluorophenyl)(piperidine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

piperidine (110-89-4) + pentafluorophenyl(tetrahydrothiophene)gold(I) → [Au(C6F5)(piperidine)] (653599-29-2)

Guidance literature:

In diethyl ether; (Ar); addn. of ligand to a soln. of gold complex in Et2O, stirring for 1.5 h at room temp.; evapn., extn. with Et2O, filtration through anhyd. MgSO4, evapn., recrystn. (CH2Cl2 layered with hexane); elem. anal.;

DOI:10.1039/b303625a

Reference yield:

pentafluorophenyl(tetrahydrothiophene)gold(I) → [Au(C6F5)(piperidine)] (653599-29-2)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: diethyl ether

In diethyl ether;

DOI:10.1039/b303625a

Reference yield:

piperidine (110-89-4) + [Au(C6F5)(4-methyl-2-methylsulfanylthiazole)] (653599-28-1) → [Au(C6F5)(piperidine)] (653599-29-2)

Guidance literature:

In diethyl ether; byproducts: 4-methyl-2-methylsulfanylthiazole; (Ar); react. of a soln. of gold complex in Et2O with ligand, stirring for 2 h at 32°C; filtration, evapn., detected by NMR;

DOI:10.1039/b303625a

upstream raw materials:

piperidine

[Au(C₆F₅)(4-methyl-2-methylsulfanylthiazole)]