Benzoic acid, 4-(dodecyloxy)-, 2,3-dimethyl-2,3-dinitrobutyl ester

Base Information

• Chemical Name: Benzoic acid, 4-(dodecyloxy)-, 2,3-dimethyl-2,3-dinitrobutyl ester
• CAS No.: 654070-74-3
• Molecular Formula: C25H40N2O7
• Molecular Weight: 480.602
• Mol file: 654070-74-3.mol

Synonyms:

Chemical Property of Benzoic acid, 4-(dodecyloxy)-, 2,3-dimethyl-2,3-dinitrobutyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzoic acid, 4-(dodecyloxy)-, 2,3-dimethyl-2,3-dinitrobutyl ester

There total 2 articles about Benzoic acid, 4-(dodecyloxy)-, 2,3-dimethyl-2,3-dinitrobutyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

4-dodecyloxybenzoyl chloride (50909-50-7) + (+/-)-2,3-dimethyl-2,3-dinitrobutanol (558426-43-0) → (+/-)-2,3-dimethyl-2,3-dinitrobutyl 4-dodecyloxybenzoate (654070-74-3)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 25 ℃;

DOI:10.1021/jo0354443

Reference yield:

(+/-)-2,3-dimethyl-2,3-dinitrobutyl tetrahydropyranyl ether (86958-60-3) → (+/-)-2,3-dimethyl-2,3-dinitrobutyl 4-dodecyloxybenzoate (654070-74-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / iodine / methanol / 6 h / 60 °C

2: 73 percent / triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 25 °C

With dmap; iodine; triethylamine; In methanol; dichloromethane;

DOI:10.1021/jo0354443

Reference yield:

(+/-)-2,3-dimethyl-2,3-dinitrobutyl 4-dodecyloxybenzoate (654070-74-3) → 4-dodecyloxy-benzoic acid 2,3-bis-hydroxyamino-2,3-dimethyl-butyl ester

Guidance literature:

With aluminum amalgam; In tetrahydrofuran; water; at 0 ℃;

DOI:10.1021/jo0354443

upstream raw materials:

4-dodecyloxybenzoyl chloride

(+/-)-2,3-dimethyl-2,3-dinitrobutanol

(+/-)-2,3-dimethyl-2,3-dinitrobutyl tetrahydropyranyl ether