3,3-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid

Base Information

• Chemical Name: 3,3-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
• CAS No.: 469-74-9
• Molecular Formula: C10H14O3
• Molecular Weight: 182.219
• NSC Number: 670151,167056
• DSSTox Substance ID: DTXSID80304715
• Nikkaji Number: J2.915.348E
• Mol file: 469-74-9.mol

Synonyms:469-74-9;3,3-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid;3,3-Dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-carboxylic acid;NSC670151;NSC167056;Oprea1_306355;Oprea1_418215;DTXSID80304715;HMS1652K04;STL553121;AKOS000267975;AKOS016038840;NSC-167056;NSC-670151;VU0494156-1;EN300-236307;3,3-dimethyl-2-oxo-norbornane-1-carboxylic acid;AF-399/40768815;F1052-0007;3,3-Dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-carboxylicacid

Chemical Property of 3,3-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid

Chemical Property:

• Vapor Pressure: 0.000109mmHg at 25°C
• Boiling Point: 313.3°Cat760mmHg
• Flash Point: 157.5°C
• PSA: 54.37000
• Density: 1.238g/cm³
• LogP: 1.46640
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 182.094294304
• Heavy Atom Count: 13
• Complexity: 293

Purity/Quality:

99% ^*data from raw suppliers

3,3-Dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-carboxylic acid 95%+ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(C2CCC(C2)(C1=O)C(=O)O)C

Technology Process of 3,3-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid

There total 8 articles about 3,3-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(3-carboxy-cyclopentyl)-2-methyl-propionic acid (473-35-8) → (+/-)-camphenonoic acid (469-74-9,124578-23-0)

Guidance literature:

durch Destillation;

Reference yield:

→ 3,3-dimethyl-2-oxo-norbornane-1-carboxylic acid (469-74-9)

Guidance literature:

With potassium hydroxide; active substance of unknown optically rotatory sense; Oxydation der gewonnen Camphencarbonsaeure mit Permanganat;

Reference yield:

→ 3,3-dimethyl-2-oxo-norbornane-1-carboxylic acid (469-74-9)

Guidance literature:

With permanganate(VII) ion; sodium carbonate;

upstream raw materials:

3,3-dimethyl-2-methylene-norbornane-1-carboxylic acid

2-(3-carboxy-cyclopentyl)-2-methyl-propionic acid

3,3-dimethyl-2-methylenebicyclo<2.2.1>heptane-1-carboxylic acid

(+)-(1R)-3,3-dimethyl-2-methylene-1-norbornanecarboxylic acid

Downstream raw materials:

(+/-)-camphenic acid

3,3-dimethyl-2-oxo-norbornane-1-carbonyl chloride