Carbamic acid, (4-hydroxy-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)

Base Information

Chemical Name:Carbamic acid, (4-hydroxy-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)
CAS No.:657396-96-8
Molecular Formula:C10H17NO3
Molecular Weight:199.24700
Hs Code.:
Mol file:657396-96-8.mol

Synonyms:(4-hydroxycyclopent-2-enyl)carbamic acid tert-butyl ester;

Suppliers and Price of Carbamic acid, (4-hydroxy-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

J&W Pharmlab
(4-Hydroxy-cyclopent-2-enyl)-carbamicacidtert-butylester 97%
5g
$ 1998.00

J&W Pharmlab
(4-Hydroxy-cyclopent-2-enyl)-carbamicacidtert-butylester 97%
1g
$ 598.00

J&W Pharmlab
(4-Hydroxy-cyclopent-2-enyl)-carbamicacidtert-butylester 97%
500mg
$ 349.00

Total 2 raw suppliers

Chemical Property of Carbamic acid, (4-hydroxy-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

PSA：58.56000
LogP:1.59140

Purity/Quality:

97% ^*data from raw suppliers

(4-Hydroxy-cyclopent-2-enyl)-carbamicacidtert-butylester 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Carbamic acid, (4-hydroxy-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)

There total 4 articles about Carbamic acid, (4-hydroxy-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 99027-90-4
2-oxa-3-azabicyclo[2.2.1]hept-5-ene-3-carboxylic acidtert-butyl ester

: 657396-96-8,154802-92-3,178152-48-2
(4-hydroxycyclopent-2-enyl)-carbamic acid tert-butyl ester

Guidance literature:: 2-oxa-3-azabicyclo[2.2.1]hept-5-ene-3-carboxylic acidtert-butyl ester; With molybdenum hexacarbonyl; In water; acetonitrile; at 20 ℃; for 0.166667h;

With sodium tetrahydroborate; In water; acetonitrile; for 3h; Heating / reflux;

Reference yield:

: 36016-38-3
tert-Butyl N-hydroxycarbamate

: 657396-96-8,154802-92-3,178152-48-2
(4-hydroxycyclopent-2-enyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / tetra-n-butylammonium periodate / CH₂Cl₂ / 1 h / 20 °C

2: disodium hydrogen phosphate; sodium amalgam / ethanol / 1.5 h / 0 °C

With disodium hydrogenphosphate; sodium amalgam; tetrabutylammonium periodite; In ethanol; dichloromethane;
DOI:10.1016/j.tet.2004.01.046

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 657396-96-8,154802-92-3,178152-48-2
(4-hydroxycyclopent-2-enyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 89 percent / hydroxylamine hydrochloride; sodium carbonate / diethyl ether; H₂O / 0 - 20 °C

2: 79 percent / tetra-n-butylammonium periodate / CH₂Cl₂ / 1 h / 20 °C

3: disodium hydrogen phosphate; sodium amalgam / ethanol / 1.5 h / 0 °C

With disodium hydrogenphosphate; sodium amalgam; hydroxylamine hydrochloride; sodium carbonate; tetrabutylammonium periodite; In diethyl ether; ethanol; dichloromethane; water;
DOI:10.1016/j.tet.2004.01.046