(-)-cis-Permethrin

Base Information

Chemical Name:(-)-cis-Permethrin
CAS No.:54774-46-8
Molecular Formula:C₂₁H₂₀Cl₂O₃
Molecular Weight:391.294
Hs Code.:
UNII:TVC0CLY3DB
DSSTox Substance ID:DTXSID2058253
Nikkaji Number:J301.801F
Wikidata:Q27290439
Metabolomics Workbench ID:144219
ChEMBL ID:CHEMBL601463

Synonyms:(m-Phenoxybenzyl)-cis,trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate;3-Phenoxybenzyl-(+-)-cis,trans-2,2-dichlorovinyl-2,2-dimethyl-cyclopropylcarboxylic acid, ester;3-Phenoxybenzyl-cis,trans-(1RS)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate;Ambush;cis permethrin;cis-(1RS)-permethrin;cis-permethrin;Cyclopropanecarboxylic Acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, (3-phenoxyphenyl)methyl ester;Elimite;FMC 33297;FMC-33297;FMC33297;NIA 33297;NIA-33297;NIA33297;Nittifor;NRDC 143;NRDC 147;NRDC-143;NRDC-147;NRDC143;NRDC147;Permethrin;Permethrin, (1R-cis)-Isomer;Permethrin, (1R-trans)-Isomer;Permethrin, (1S-cis)-Isomer;Permethrin, (1S-trans)-Isomer;Permethrin, (cis)-Isomer;Permethrin, (cis-(+-))-Isomer;Permethrin, (trans)-Isomer;Permethrin, (trans-(+-))-Isomer;permethrin, cis-(1RS)-isomer;Permethrin, trans-(1RS)-Isomer;PP 557;PP-557;PP557;S 3151;S-3151;S3151;trans permethrin;trans-(1RS)-Permethrin;trans-permethrin

Suppliers and Price of (-)-cis-Permethrin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of (-)-cis-Permethrin

Chemical Property:

Vapor Pressure:7.41E-09mmHg at 25°C
Boiling Point:465.9°Cat760mmHg
Flash Point:159.4°C
Density:1.293g/cm³
XLogP3:6.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:390.0789499
Heavy Atom Count:26
Complexity:521

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C(C1C(=O)OCC2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Cl)Cl)C
Isomeric SMILES:CC1([C@@H]([C@@H]1C(=O)OCC2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Cl)Cl)C
Recent ClinicalTrials:Bio-equivalence Study Comparing Permethrin Cream, 5% With Elimite in Patients With Active Scabies.

Technology Process of (-)-cis-Permethrin

There total 9 articles about (-)-cis-Permethrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 51632-16-7
3-phenoxybenzyl bromide

: 59042-49-8
cis-permethrinic acid

: 51877-74-8,52341-32-9,52341-33-0,54774-45-7,54774-46-8,54774-47-9,61949-76-6,61949-77-7,52645-53-1,93388-66-0
(1RS)-cis-permethrin

Guidance literature:: With triethylamine; In acetone; at 35 ℃; for 3h;

Reference yield:

: 55667-43-1
1,1-dichloro-4-methyl-penta-1,3-diene

: 51877-74-8,52341-32-9,52341-33-0,54774-45-7,54774-46-8,54774-47-9,61949-76-6,61949-77-7,52645-53-1,93388-66-0
(1RS)-cis-permethrin

Guidance literature:: Multi-step reaction with 6 steps

1: 20 percent / Cu₂O, CuCl, dibutylamine / 1 h / 100 - 110 °C

2: 87 percent / Zn/Cu / methanol

3: 80 percent / HCl / 4 h / Ambient temperature

4: NaOMe / methanol / 2 h / 50 °C

5: 95 percent / NaOH / methanol / 8 h / 40 °C

6: 3.52 g / Et₃N / acetone / 3 h / 35 °C

With copper(I) oxide; hydrogenchloride; sodium hydroxide; sodium methylate; copper; dibutylamine; triethylamine; copper(l) chloride; zinc; In methanol; acetone;

Reference yield:

: 61976-30-5
methyl 2,2-dimethyl-3-(2,2-dichloroethenyl)cyclopropane-1-carboxylate

: 51877-74-8,52341-32-9,52341-33-0,54774-45-7,54774-46-8,54774-47-9,61949-76-6,61949-77-7,52645-53-1,93388-66-0
(1RS)-cis-permethrin

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / NaOH / methanol / 8 h / 40 °C

2: 3.52 g / Et₃N / acetone / 3 h / 35 °C

With sodium hydroxide; triethylamine; In methanol; acetone;