(2Z,5E)-2,5-bis[ethoxy(hydroxy)methylidene]cyclohexane-1,4-dione

Base Information

Chemical Name:(2Z,5E)-2,5-bis[ethoxy(hydroxy)methylidene]cyclohexane-1,4-dione
CAS No.:16877-79-5
Molecular Formula:C12H16 O6
Molecular Weight:256.255
Hs Code.:
Mol file:16877-79-5.mol

Synonyms:1,4-Cyclohexadiene-1,4-dicarboxylicacid, 2,5-dihydroxy-, diethyl ester (6CI,8CI,9CI);1,4-Bis(ethoxycarbonyl)-2,5-dihydroxy-1,4-cyclohexadiene;2,5-Dihydroxy-1,4-cyclohexadiene-1,4-dicarboxylic acid diethyl ester; Diethyl2,5-dihydroxy-1,4-cyclohexadiene-1,4-dicarboxylate; Diethyl succinoylsuccinate;NSC 177976

Suppliers and Price of (2Z,5E)-2,5-bis[ethoxy(hydroxy)methylidene]cyclohexane-1,4-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of (2Z,5E)-2,5-bis[ethoxy(hydroxy)methylidene]cyclohexane-1,4-dione

Chemical Property:

Vapor Pressure:6.74E-09mmHg at 25°C
Boiling Point:422.2°Cat760mmHg
Flash Point:160.2°C
Density:1.341g/cm³

Purity/Quality:: 90%,98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (2Z,5E)-2,5-bis[ethoxy(hydroxy)methylidene]cyclohexane-1,4-dione

There total 7 articles about (2Z,5E)-2,5-bis[ethoxy(hydroxy)methylidene]cyclohexane-1,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 123-25-1
succinic acid diethyl ester

: 16877-79-5
diethyl 2,5-dihydroxy-1,4-cyclohexadiene-1,4-dicarboxylate

Guidance literature:: With sodium hydride; In dimethyl sulfoxide; at 0 - 50 ℃;
DOI:10.1055/s-2007-983901

Reference yield: 80.0%

: 638-07-3
ethyl (2-chloroaceto)acetate

: 16877-79-5
diethyl 2,5-dihydroxy-1,4-cyclohexadiene-1,4-dicarboxylate

: 81302-78-5
ethyl 4-iodo-3-oxobutanoate

Guidance literature:: With sodium iodide; In acetone; at 65 ℃; for 0.5h; Microwave irradiation;
DOI:10.1039/c6nj02048h

Reference yield: 27.0%

: 638-07-3
ethyl (2-chloroaceto)acetate

: 51608-60-7
N-(benzylidene)-p-methylbenzenesulfonamide

: 16877-79-5
diethyl 2,5-dihydroxy-1,4-cyclohexadiene-1,4-dicarboxylate

: 1642868-19-6
C₂₀H₂₁NO₅S

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium tert-butylate; In 1,4-dioxane; at 50 ℃; for 10h; Schlenk technique; Inert atmosphere;
DOI:10.3762/bjoc.10.150