9,12,15 HEXADECATRIENOIC ACID

Base Information

• Chemical Name: 9,12,15 HEXADECATRIENOIC ACID
• CAS No.: 66753-70-6
• Molecular Formula: C16H26O2
• Molecular Weight: 250.37600
• Hs Code.: 2916190090
• Mol file: 66753-70-6.mol

Synonyms:Palmitoleoyl chloride;Palmitolinolensaeure;palmitoleic chloride;palmitoleyl chloride;

Chemical Property of 9,12,15 HEXADECATRIENOIC ACID

Chemical Property:

• PSA: 37.30000
• LogP: 4.88030

Purity/Quality:

99% ^*data from raw suppliers

9,12,15 HEXADECATRIENOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9,12,15 HEXADECATRIENOIC ACID

There total 5 articles about 9,12,15 HEXADECATRIENOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(9Z,12Z)-methyl hexadeca-9,12,15-trienoate → (9Z,12Z)-hexadeca-9,12,15-trienoic acid (66753-70-6)

Guidance literature:

With water; lithium hydroxide; In tetrahydrofuran; at 0 - 20 ℃; for 12.5h;

Reference yield:

(9Z,12Z)-methyl hexadeca-9,12,15-trienoate (93541-28-7) → (9Z,12Z)-hexadeca-9,12,15-trienoic acid (66753-70-6)

Guidance literature:

With LiOH; In tetrahydrofuran;

Reference yield:

hex-5-en-2-ynyl bromide (69643-52-3) → (9Z,12Z)-hexadeca-9,12,15-trienoic acid (66753-70-6)

Guidance literature:

Multi-step reaction with 3 steps

1: ammonium chloride; sodium iodide; CuI; CsCO₃ / N,N-dimethyl-formamide

2: 2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol / ethyl acetate

3: LiOH / tetrahydrofuran

With CuI; CsCO₃; LiOH; ammonium chloride; sodium iodide; 2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol; In tetrahydrofuran; ethyl acetate; N,N-dimethyl-formamide;

upstream raw materials:

hex-5-en-2-ynyl bromide

(9Z,12Z)-methyl hexadeca-9,12,15-trienoate

methyl dec-9-ynoate

methyl hexadeca-15-en-9,12-diynoate

Refernces

• 1、 -. "Two Novel Alkylresorcinol Synthase Genes from Sorghum; Cloning, Expression, Transformation and Characterization". . . Retrieved 2011/10/04.