Acetic acid 1-acetoxy-prop-2-ynyl ester

Base Information

Chemical Name:Acetic acid 1-acetoxy-prop-2-ynyl ester
CAS No.:67088-67-9
Molecular Formula:C₇H₈O₄
Molecular Weight:156.138
Hs Code.:
DSSTox Substance ID:DTXSID20489858
Wikidata:Q82333364

Synonyms:67088-67-9;ACETIC ACID 1-ACETOXY-PROP-2-YNYL ESTER;Prop-1-yne-3,3-diyl diacetate;DTXSID20489858;AKOS006330573

Suppliers and Price of Acetic acid 1-acetoxy-prop-2-ynyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
ACETIC ACID 1-ACETOXY-PROP-2-YNYL ESTER 95.00%
5MG
$ 503.67

Total 3 raw suppliers

Chemical Property of Acetic acid 1-acetoxy-prop-2-ynyl ester

Chemical Property:

Vapor Pressure:0.243mmHg at 25°C
Boiling Point:206oC at 760 mmHg
Flash Point:96.9oC
PSA：52.60000
Density:1.154g/cm3
LogP:0.07190
XLogP3:0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:156.04225873
Heavy Atom Count:11
Complexity:194

Purity/Quality:

99% ^*data from raw suppliers

ACETIC ACID 1-ACETOXY-PROP-2-YNYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)OC(C#C)OC(=O)C

Technology Process of Acetic acid 1-acetoxy-prop-2-ynyl ester

There total 1 articles about Acetic acid 1-acetoxy-prop-2-ynyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 624-67-9
Propargylic aldehyde

: 108-24-7
acetic anhydride

: 67088-67-9
propynal diacetate

Guidance literature:: With sulfuric acid;
DOI:10.1007/BF00906352

Reference yield: 64.0%

: 62858-89-3
PPh₃Co(Salphen)N₃

: 67088-67-9
propynal diacetate

: 80462-23-3
(C₆H₅)3PCo((OC₆H₄CHN)2C₆H₄)CCCH(CO₂CH₃)2

Guidance literature:: In dimethyl sulfoxide; byproducts: NH3; to soln. azide complex in DMSO added 2 molar equiv. alkyne and soln. stirred for 1 day at 100°C; CH2Cl2/pet. ether added, ppt. recrystd. from CHCl3/pet. ether; elem. anal.;
DOI:10.1021/ic00133a069