2-Pentanone, 4-phenyl-, (R)-

Base Information

Chemical Name:2-Pentanone, 4-phenyl-, (R)-
CAS No.:67110-72-9
Molecular Formula:C11H14O
Molecular Weight:162.232
Hs Code.:
DSSTox Substance ID:DTXSID00444622
Nikkaji Number:J775.219I
Wikidata:Q82262809

Synonyms:2-Pentanone, 4-phenyl-, (R)-;67110-72-9;(R)-4-Phenyl-2-pentanone;SCHEMBL11484603;DTXSID00444622

Suppliers and Price of 2-Pentanone, 4-phenyl-, (R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 2-Pentanone, 4-phenyl-, (R)-

Chemical Property:

XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:162.104465066
Heavy Atom Count:12
Complexity:145

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CC(=O)C)C1=CC=CC=C1
Isomeric SMILES:C[C@H](CC(=O)C)C1=CC=CC=C1

Technology Process of 2-Pentanone, 4-phenyl-, (R)-

There total 50 articles about 2-Pentanone, 4-phenyl-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 625-33-2
3-penten-2-one

: 98-80-6
phenylboronic acid

: 67110-72-9
(4R)-4-phenylpentan-2-one

Guidance literature:: With BF₄^(1-)*C₆₈H₄₄N₂O₄P₂Rh⁽¹⁺⁾; water; potassium hydroxide; In 1,4-dioxane; at 60 ℃; for 1h; optical yield given as %ee; enantioselective reaction; Anaerobic conditions; Combinatorial reaction / High throughput screening (HTS);
DOI:10.1021/om100248u

Reference yield: 92.0%

: 51384-73-7,55543-90-3,827-69-0
4-phenyl-3-penten-2-one

: 32587-80-7
(S)-4-phenylpentan-2-one

: 67110-72-9
(4R)-4-phenylpentan-2-one

Guidance literature:: With bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2-[(2S)-2-{[bis(2-methylphenyl)phosphanyl]methyl}pyrrolidin-1-yl]-1,3-benzothiazole; hydrogen; In dichloromethane; at 20 ℃; for 2h; under 37503.8 Torr; Reagent/catalyst; enantioselective reaction; Autoclave;
DOI:10.1002/hlca.201200437

Reference yield: 90.0%

: 827-69-0
(E)-4-phenyl-3-penten-2-one

: 67110-72-9
(4R)-4-phenylpentan-2-one

Guidance literature:: (E)-4-phenyl-3-penten-2-one; With (2S)-1-[(1S)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene; diethoxymethylane; copper(II) acetate monohydrate; In diethyl ether; at -25 ℃; for 24h; Inert atmosphere;

With ammonium fluoride; In methanol; diethyl ether; at -25 ℃; optical yield given as %ee; regioselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2011.10.056