2(3H)-Furanone,3,4-bis(1,3-benzodioxol-5-ylmethyl)dihydro-, (3S,4S)-

Base Information

• Chemical Name: 2(3H)-Furanone,3,4-bis(1,3-benzodioxol-5-ylmethyl)dihydro-, (3S,4S)-
• CAS No.: 103063-07-6
• Molecular Formula: C₂₀H₁₈O₆
• Molecular Weight: 354.359
• Mol file: 103063-07-6.mol

Synonyms:2(3H)-Furanone,3,4-bis(1,3-benzodioxol-5-ylmethyl)dihydro-, (3S-trans)-; 2(3H)-Furanone, dihydro-3,4-dipiperonyl-,trans-(+)- (8CI); (+)-Hinokinin; Heliobuphthalmin lactone

Chemical Property of 2(3H)-Furanone,3,4-bis(1,3-benzodioxol-5-ylmethyl)dihydro-, (3S,4S)-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2(3H)-Furanone,3,4-bis(1,3-benzodioxol-5-ylmethyl)dihydro-, (3S,4S)-

There total 63 articles about 2(3H)-Furanone,3,4-bis(1,3-benzodioxol-5-ylmethyl)dihydro-, (3S,4S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3,4-bis[(3,4-methylenedioxy)benzyl]-3-phenylselanyl-γ-butyrolactone → (+/-)-hinokinin (580-73-4,24563-00-6,24563-02-8,24563-14-2,24641-36-9,26543-89-5,26543-90-8,94534-80-2,103063-07-6,120409-93-0)

Guidance literature:

With sodium tetrahydroborate; nickel dichloride; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

DOI:10.1016/S0040-4020(99)00721-8

Reference yield: 93.0%

(2R*,3S*)-2,3-bis(3′,4′-methylenedioxybenzyl)butane-1,4-diol (24562-96-7) → (+/-)-isohinokinin (580-73-4,24563-00-6,24563-02-8,24563-14-2,24641-36-9,26543-89-5,26543-90-8,94534-80-2,103063-07-6,120409-93-0)

Guidance literature:

With Celite; silver carbonate; In benzene; for 16h; Reflux;

DOI:10.3184/030823409X12506792542747

Reference yield: 90.0%

trans-2-[3-(α-hydroxy-3,4-(methylenedioxy)benzyl)-4-(3,4-(methylenedioxy)benzyl)]-butyrolactone → (+/-)-hinokinin (580-73-4,24563-00-6,24563-02-8,24563-14-2,24641-36-9,26543-89-5,26543-90-8,94534-80-2,103063-07-6,120409-93-0)

Guidance literature:

With hydrogen; acetic acid; palladium dihydroxide; In tetrahydrofuran; at 20 ℃; under 760 Torr;

DOI:10.1081/SCC-200051037

upstream raw materials:

(E)-4-((benzo[d][1,3]dioxol-6-yl)methyl)-3-((benzo[d][1,3]dioxol-6-yl)methylene)dihy-drofuran-2(3H)-one

piperonal

(3,4-methylenedioxybenzyl)magnesium chloride

(2R*,3S*)-2,3-bis(3′,4′-methylenedioxybenzyl)butane-1,4-diol

Downstream raw materials:

ariensin