Azacymantrene

Base Information

• Chemical Name: Azacymantrene
• CAS No.: 32761-36-7
• Molecular Formula: C₇H₄MnNO₃
• Molecular Weight: 205.052
• Mol file: 32761-36-7.mol

Synonyms:

Chemical Property of Azacymantrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Azacymantrene

There total 1 articles about Azacymantrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

pyrrole (109-97-7,30604-81-0) + [manganese(I)tricarbonyl(acetonitrile)3](hexafluorophosphate) (54039-60-0,49835-29-2) → dimanganese decacarbonyl (10170-69-1) + (η5-pyrrolyl)tricarbonylmanganese(I) (32761-36-7)

Guidance literature:

With potassium; In tetrahydrofuran; toluene; byproducts: KPF6, MeCN, H2; N2-atmosphere; dropwise addn. of pyrrole in THF to K in cold toluene, refluxing, addn. of Mn-complex in THF, stirring (room temp., 2 d); solvent removal (vac.), addn. of hexane, filtration, concn. (vac.), chromy. (Al2O3, hexane, then CH2Cl2/hexane=1:4);

DOI:10.1016/0022-328X(85)80340-5

Reference yield: 71.0%

(η5-pyrrolyl)tricarbonylmanganese(I) (32761-36-7) + methyltrioxorhenium(VII) (70197-13-6) → methyl{tricarbonyl(η5-pyrrolyl)manganese}(trioxo)rhenium(VII)

Guidance literature:

In diethyl ether; stirred for 20 h at room temp.; filtered, addn. of hexane, 10-30 h at -35°C; elem. anal.;

DOI:10.1016/0022-328X(89)87230-4

Reference yield: 54.0%

(η5-pyrrolyl)tricarbonylmanganese(I) (32761-36-7) + 2,4,6-Trinitrophenol (88-89-1) → C4H4NMn(CO)3H(1+)*C6H2(NO2)3O(1-) + C4H4NMn2(CO)6C6H2O(NO2)3

Guidance literature:

In dichloromethane; A mixt. of reagents in CH2Cl2 was kept at room temp. for 3 days;; solvent was removed under Ar, ppt. was washed with water, then hexane, dried in vac., recrystd. from CH2Cl2; elem. anal.;;

DOI:10.1016/S0022-328X(00)83470-1

upstream raw materials:

pyrrole

[manganese(I)tricarbonyl(acetonitrile)3](hexafluorophosphate)

Downstream raw materials:

(η5-C4H4N)Mn(CO)2P(C6H5)3

Mn(CO)2(P(C₆H₁₁)3)(C₄H₄N)

Mn(CO)(P(C₆H₁₁)3)2(C₄H₄N)