Magnesium, iodo(4-methylphenyl)-

Base Information

• Chemical Name: Magnesium, iodo(4-methylphenyl)-
• CAS No.: 6749-78-6
• Molecular Formula: C7H7IMg
• Molecular Weight: 242.342
• Mol file: 6749-78-6.mol

Synonyms:

Chemical Property of Magnesium, iodo(4-methylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Magnesium, iodo(4-methylphenyl)-

There total 2 articles about Magnesium, iodo(4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-tolyl iodide (624-31-7) → 4-methylphenylmagnesium iodide (6749-78-6)

Guidance literature:

With iodine; magnesium; In diethyl ether; for 3h; Inert atmosphere;

DOI:10.1021/acs.orglett.5b00434

Reference yield:

4-tolyl iodide (624-31-7) → 4-methylphenylmagnesium iodide (6749-78-6)

Guidance literature:

Reference yield: 84.0%

isochromane (493-05-0) + 4-methylphenylmagnesium iodide (6749-78-6) → 3,4-dihydro-1-(4-methylphenyl)-1H-2-benzopyran (1445853-51-9)

Guidance literature:

isochromane; With 2-azatricyclo[3.3.1.1^3,7]decan-2-ol; [bis-(trifluoroacetoxy)iodo]benzene; In 1,2-dichloro-ethane; at 50 ℃; for 15h; Inert atmosphere;

4-methylphenylmagnesium iodide; With 2-azatricyclo[3.3.1.1^3,7]decan-2-ol; [bis-(trifluoroacetoxy)iodo]benzene; In diethyl ether; 1,2-dichloro-ethane; at -30 ℃; for 3h; Inert atmosphere;

DOI:10.1021/acs.orglett.5b00434

upstream raw materials:

4-tolyl iodide

Downstream raw materials:

4-Methylphenethyl alcohol

9-hydroxy-9-(4-methylphenyl)xanthene

N-(2-hydroxy-phenyl)-4-methyl-benzamide

4,4'-dimethyl-benzilic acid m-anisidide

Refernces