Benzyl 5-chloro-5-oxopentanoate

Base Information

Chemical Name:Benzyl 5-chloro-5-oxopentanoate
CAS No.:67852-85-1
Molecular Formula:C12H13ClO3
Molecular Weight:240.686
Hs Code.:
DSSTox Substance ID:DTXSID00515220
Wikidata:Q82375997

Synonyms:BENZYL 5-CHLORO-5-OXOPENTANOATE;67852-85-1;Pentanoic acid, 5-chloro-5-oxo-, phenylmethyl ester;SCHEMBL11343298;DTXSID00515220

Suppliers and Price of Benzyl 5-chloro-5-oxopentanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Benzyl 5-chloro-5-oxopentanoate

Chemical Property:

XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:240.0553220
Heavy Atom Count:16
Complexity:234

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)COC(=O)CCCC(=O)Cl

Technology Process of Benzyl 5-chloro-5-oxopentanoate

There total 3 articles about Benzyl 5-chloro-5-oxopentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 54322-10-0
glutaric acid monobenzyl ester

: 67852-85-1
glutaric acid chloride monobenzyl ester

Guidance literature:: With oxalyl dichloride; N,N-dimethyl-formamide; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1021/ja00113a001

Reference yield:

: 108-55-4
glutaric anhydride,

: 67852-85-1
glutaric acid chloride monobenzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: dmap; triethylamine / dichloromethane / 48 h / 0 - 20 °C

2: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 1.75 h / 0 - 20 °C / Inert atmosphere

With dmap; oxalyl dichloride; triethylamine; N,N-dimethyl-formamide; In dichloromethane;
DOI:10.1039/c1cc10691k

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 67852-85-1
glutaric acid chloride monobenzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine; dmap / dichloromethane

2: N,N-dimethyl-formamide; oxalyl dichloride / dichloromethane

With dmap; oxalyl dichloride; triethylamine; N,N-dimethyl-formamide; In dichloromethane;
DOI:10.1111/cbdd.13208