Benzoic acid, 2-chloro-, copper(2+) salt

Base Information

• Chemical Name: Benzoic acid, 2-chloro-, copper(2+) salt
• CAS No.: 6835-26-3
• Molecular Formula: 2C₇H₄ClO₂*Cu
• Molecular Weight: 374.667
• Mol file: 6835-26-3.mol

Synonyms:

Chemical Property of Benzoic acid, 2-chloro-, copper(2+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzoic acid, 2-chloro-, copper(2+) salt

There total 1 articles about Benzoic acid, 2-chloro-, copper(2+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

copper(ll) sulfate pentahydrate + ortho-chlorobenzoic acid (118-91-2) → copper(II)(o-chlorobenzoate)2 (6835-26-3,50671-63-1)

Guidance literature:

In sodium hydroxide; water;

Reference yield: 85.0%

1-methyl-piperazine (109-01-3) + copper(II)(o-chlorobenzoate)2 (6835-26-3,50671-63-1) → Cu(2-chlorobenzoate)2(1-methylpiperazine)0.5

Guidance literature:

In diethyl ether; Cu-compound suspended in ether, soln. of ligand in ether added dropwise in interval of 10 min for 2.5 h, stirred for 2 h; filtered, washed with Et2O, dried under vac. over CaCl2; elem. anal.;

Reference yield: 80.0%

1-ethyl-piperidine (766-09-6) + copper(II)(o-chlorobenzoate)2 (6835-26-3,50671-63-1) → [Cu(2-chlorobenzoate)2(1-ethylpiperidine)] (873544-13-9)

Guidance literature:

In diethyl ether; Cu(II) benzoate suspended in ether; 50% excess of heterocyclic base in ether added dropwise over 2.5 h with intervals of 10 min to stirred suspension; mixt. stirred for 2 h; filtered; washed (Et2O); dried (vac.); placed in desiccator (anhyd. CaCl2); elem. anal.;

upstream raw materials:

ortho-chlorobenzoic acid

Downstream raw materials:

2,2'-thiodibenzoic acid

bis(o-chlorobenzoato)bis(2.4.6-trimethylpyridine) copper(II)

[bis(2-chlorobenzoate)quinoline N-oxide-copper(II)]2

bis[bis(o-chlorobenzoato)-(4-cyanopyridine) copper(II)]

Refernces

• 1、 Manhas,Kalia,Sardana,Kaushal. "Magnetic and spectroscopic characterization of copper(II) chlorobenzoate adducts with substituted piperidines". . p. 1576 - 1581. Retrieved 2007/10/03.
• 2、 -. "Cyclic sulphur compounds". . . Retrieved 2008/06/13.