2-Cyclopropene-1-carboxylic acid, 2-phenyl-1-(2-thienyl)-

Base Information

• Chemical Name: 2-Cyclopropene-1-carboxylic acid, 2-phenyl-1-(2-thienyl)-
• CAS No.: 691889-40-4
• Molecular Formula: C14H10O2S
• Molecular Weight: 242.298
• DSSTox Substance ID: DTXSID10461986

Synonyms:2-Cyclopropene-1-carboxylic acid, 2-phenyl-1-(2-thienyl)-;691889-40-4;DTXSID10461986

Chemical Property of 2-Cyclopropene-1-carboxylic acid, 2-phenyl-1-(2-thienyl)-

Chemical Property:

• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 242.04015073
• Heavy Atom Count: 17
• Complexity: 357

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC2(C3=CC=CS3)C(=O)O

Technology Process of 2-Cyclopropene-1-carboxylic acid, 2-phenyl-1-(2-thienyl)-

There total 1 articles about 2-Cyclopropene-1-carboxylic acid, 2-phenyl-1-(2-thienyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethyl α-(2-thienyl)diazoacetate → (+/-)-1-(2-thienyl)-2-phenylcycloprop-2-ene-1-carboxylic acid (691889-40-4)

Guidance literature:

Multi-step reaction with 2 steps

1: dirhodium tetracetate / CH₂Cl₂ / 1 h

2: 317 mg / aq. KOH / methanol / 20 °C

With dirhodium tetraacetate; potassium hydroxide; In methanol; dichloromethane;

DOI:10.1021/ja049779t

Reference yield: 66.0%

iodobenzene (591-50-4) + (+/-)-1-(2-thienyl)-2-phenylcycloprop-2-ene-1-carboxylic acid (691889-40-4) → 1-(2-thienyl)-2,3-diphenylcycloprop-2-ene-1-carboxylic acid

Guidance literature:

(+/-)-1-(2-thienyl)-2-phenylcycloprop-2-ene-1-carboxylic acid; With methyllithium; In tetrahydrofuran; diethyl ether; at -78 - 20 ℃;

iodobenzene; With zinc(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; at -78 - 20 ℃; for 2h;

DOI:10.1021/ol047837+

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