2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole

Base Information

Chemical Name:2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole
CAS No.:69626-77-3
Molecular Formula:C13H11O3P
Molecular Weight:246.202
Hs Code.:
DSSTox Substance ID:DTXSID70529758
Wikidata:Q82400421

Synonyms:69626-77-3;2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole;DTXSID70529758

Suppliers and Price of 2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole

Chemical Property:

XLogP3:3.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:246.04458121
Heavy Atom Count:17
Complexity:229

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)COP2OC3=CC=CC=C3O2

Technology Process of 2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole

There total 3 articles about 2-(Benzyloxy)-2H-1,3,2-benzodioxaphosphole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1641-40-3
pyrocatechol phosphorochloridite

: 100-51-6,185532-71-2
benzyl alcohol

: 69626-77-3
2-benzyloxy-4,5-benzo-1,3,2-dioxaphospholane

Guidance literature:: With N,N-diethylaniline; In benzene; at 20 ℃; for 3h;
DOI:10.1007/BF00959730

Reference yield:

: 120-80-9,19481-10-8,37349-32-9
benzene-1,2-diol

: 69626-77-3
2-benzyloxy-4,5-benzo-1,3,2-dioxaphospholane

Guidance literature:: Multi-step reaction with 2 steps

1: phosphorus trichloride; triethylamine / toluene / 24 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

2: triethylamine / dichloromethane / Inert atmosphere; Schlenk technique

With triethylamine; phosphorus trichloride; In dichloromethane; toluene;
DOI:10.1039/c9dt03577j