1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester

Base Information Edit

Chemical Name:1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester
CAS No.:69937-82-2
Molecular Formula:C33H29N3O2
Molecular Weight:499.60200
Hs Code.:
Mol file:69937-82-2.mol

Synonyms:

Suppliers and Price of 1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidineMethylEster
50mg
$ 165.00

Medical Isotopes, Inc.
1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidineMethylEster
50 mg
$ 650.00

Total 0 raw suppliers

Chemical Property of 1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester Edit

Chemical Property:

PSA：56.48000
LogP:5.92650
Storage Temp.:-20°C Freezer, Under inert atmosphere

Purity/Quality:: 1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidineMethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses 1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester can be used in the preparation of optically pure L-(+)-Ergothioneine. L-Histidine Methyl Ester (H456020) derivative. Used in the preparation of optically pure L-(+)-Ergothioneine.

Technology Process of 1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester

There total 8 articles about 1-(Triphenylmethyl)-N-(phenylmethylene)-L-histidine Methyl Ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76-83-5
trityl chloride

: 69937-82-2
(S)-2-{[1-Phenyl-meth-(E)-ylidene]-amino}-3-(1-trityl-1H-imidazol-4-yl)-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / Et₃N / benzene / 1 h / 80 °C

2: 0.78 g / H₂ / 10percent Pd/C / methanol / 2.5 h / 25 °C / 760 Torr

3: methanol / 1.5 h / 25 °C

With hydrogen; triethylamine; palladium on activated charcoal; In methanol; benzene;
DOI:10.1016/0968-0896(95)00183-2

Reference yield:

: 40917-50-8
1,N^α-bis-benzyloxycarbonyl-histidine methyl ester

: 69937-82-2
(S)-2-{[1-Phenyl-meth-(E)-ylidene]-amino}-3-(1-trityl-1H-imidazol-4-yl)-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / 1N aq. NaOH / methanol / 0.01 h / -20 °C

2: 99 percent / Et₃N / benzene / 1 h / 80 °C

3: 0.78 g / H₂ / 10percent Pd/C / methanol / 2.5 h / 25 °C / 760 Torr

4: methanol / 1.5 h / 25 °C

With sodium hydroxide; hydrogen; triethylamine; palladium on activated charcoal; In methanol; benzene;
DOI:10.1016/0968-0896(95)00183-2

Reference yield:

: 71-00-1
L-histidine

: 69937-82-2
(S)-2-{[1-Phenyl-meth-(E)-ylidene]-amino}-3-(1-trityl-1H-imidazol-4-yl)-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / SOCl₂ / 36 h / 40 °C

2: 49 percent / aq. NaHCO₃ / acetone / 12 h / 25 °C

3: 80 percent / 1N aq. NaOH / methanol / 0.01 h / -20 °C

4: 99 percent / Et₃N / benzene / 1 h / 80 °C

5: 0.78 g / H₂ / 10percent Pd/C / methanol / 2.5 h / 25 °C / 760 Torr

6: methanol / 1.5 h / 25 °C

With sodium hydroxide; thionyl chloride; hydrogen; sodium hydrogencarbonate; triethylamine; palladium on activated charcoal; In methanol; acetone; benzene;
DOI:10.1016/0968-0896(95)00183-2