1-Undecyn-3-ol, (3S)-

Base Information

• Chemical Name: 1-Undecyn-3-ol, (3S)-
• CAS No.: 70095-33-9
• Molecular Formula: C11H20O
• Molecular Weight: 168.279
• DSSTox Substance ID: DTXSID70472775
• Nikkaji Number: J1.793.622K
• Wikidata: Q82301912
• Mol file: 70095-33-9.mol

Synonyms:1-Undecyn-3-ol, (3S)-;70095-33-9;DTXSID70472775

Chemical Property of 1-Undecyn-3-ol, (3S)-

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 168.151415257
• Heavy Atom Count: 12
• Complexity: 131

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC(C#C)O
• Isomeric SMILES: CCCCCCCC[C@@H](C#C)O

Technology Process of 1-Undecyn-3-ol, (3S)-

There total 19 articles about 1-Undecyn-3-ol, (3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(R)-1-trimethylsilyl-1-undecyn-3-ol (74794-25-5) → (R)-(+)-1-undecyn-3-ol (53735-49-2,60705-48-8,70095-33-9,74364-80-0)

Guidance literature:

With potassium carbonate; In methanol;

DOI:10.1055/s-2002-33656

Reference yield: 95.0%

Acetic acid (R)-1-trimethylsilanylethynyl-nonyl ester (188349-85-1) → (R)-(+)-1-undecyn-3-ol (53735-49-2,60705-48-8,70095-33-9,74364-80-0)

Guidance literature:

With potassium carbonate; In methanol; for 2h; Ambient temperature;

DOI:10.1016/S0957-4166(96)00475-2

Reference yield: 76.0%

(2S-trans)-3-octyloxiranemethylchloride (132437-19-5) → (R)-(+)-1-undecyn-3-ol (53735-49-2,60705-48-8,70095-33-9,74364-80-0)

Guidance literature:

With lithium amide; ammonia; In tetrahydrofuran; at -33 ℃; for 1h;

DOI:10.1016/S0040-4020(01)87888-1

upstream raw materials:

(R)-4-(1-Trimethylsilanylethynyl-nonyloxy)-pentan-2-one

(2S-trans)-3-octyloxiranemethylchloride

(R)-1-trimethylsilyl-1-undecyn-3-ol

(R)-1-undecyn-3-ol hemiphthalate

Downstream raw materials:

(±)-methyl (E)-2,4,5-tetradecatrienoate

(E)-(R)-(-)-methyl 2,4,5-tetradecatrienoate

(-)-isoavenaciolide

(S)-methyl 2-(1-((tert-butyldimethylsilyl)oxy)nonyl)-6-methoxybenzoate