Benzonitrile, 4-(diazomethyl)-

Base Information

Chemical Name:Benzonitrile, 4-(diazomethyl)-
CAS No.:70135-28-3
Molecular Formula:C8H5N3
Molecular Weight:143.148
Hs Code.:
DSSTox Substance ID:DTXSID20460420
Nikkaji Number:J1.562.331D

Synonyms:Benzonitrile, 4-(diazomethyl)-;70135-28-3;alpha-(p-cyano)phenyldiazomethane;DTXSID20460420

Suppliers and Price of Benzonitrile, 4-(diazomethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzonitrile, 4-(diazomethyl)-

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:143.048347172
Heavy Atom Count:11
Complexity:211

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC=C1C=[N+]=[N-])C#N

Technology Process of Benzonitrile, 4-(diazomethyl)-

There total 4 articles about Benzonitrile, 4-(diazomethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: C₁₇H₁₇N₃O₂S

: 70135-28-3
(4-cyanophenyl)diazomethane

Guidance literature:: With N,N,N',N'-tetramethylguanidine; In dichloromethane; formamide; at 65 ℃;
DOI:10.1002/anie.201608444

Reference yield: 67.0%

: 41780-79-4
N'-(4-cyanobenzylidene)-4-methylbenzenesulfonohydrazide

: 70135-28-3
(4-cyanophenyl)diazomethane

Guidance literature:: With sodium ethane-1,2-diolate; In hexane; at 90 ℃; for 0.0833333h;
DOI:10.1002/ejoc.200300448

Reference yield:

: 105-07-7
4-cyanobenzaldehyde

: 70135-28-3
(4-cyanophenyl)diazomethane

Guidance literature:: Multi-step reaction with 2 steps

1: acetic acid / Heating

2: 14percent NaOH, benzyl triethyl ammonium chloride / benzene / 2 h / 65 - 70 °C

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In acetic acid; benzene;