TetramethylBicyclo[2.2.2]-7-octene-2,3,5,6-tetracarboxylate

Base Information

Chemical Name:TetramethylBicyclo[2.2.2]-7-octene-2,3,5,6-tetracarboxylate
CAS No.:72598-54-0
Molecular Formula:C₁₆H₂₀O₈
Molecular Weight:340.33
Hs Code.:
Mol file:72598-54-0.mol

Synonyms:Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylicacid, tetramethyl ester (9CI); Tetramethylbicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylate

Suppliers and Price of TetramethylBicyclo[2.2.2]-7-octene-2,3,5,6-tetracarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of TetramethylBicyclo[2.2.2]-7-octene-2,3,5,6-tetracarboxylate

Chemical Property:

PSA：105.20000
LogP:-0.04100

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of TetramethylBicyclo[2.2.2]-7-octene-2,3,5,6-tetracarboxylate

There total 10 articles about TetramethylBicyclo[2.2.2]-7-octene-2,3,5,6-tetracarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 56745-93-8
2,3,5,6-exo-bicyclo<2.2.2>-7-octene-2,3,5,6-tetracarboxylic acid tetramethyl ester

: 56782-36-6
2,6-exo-3,5-endo-bicyclo<2.2.2>-7-octene-2,3,5,6-tetracarboxylic acid tetramethyl ester

: 56745-93-8,56782-33-3,56782-35-5,56782-36-6,72598-54-0,81203-29-4,108211-26-3,108211-27-4
tetramethyl all-trans-bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylate

Guidance literature:: With sodium methylate; In methanol; at 65 ℃;
DOI:10.1016/S0040-4039(00)96090-8

Reference yield:

: 3573-76-0,63527-57-1,1719-83-1
(1r,2R,3S,4r,5R,6S)-bicyclo<2.2.2>oct-2-ene-2,3,5,6-tetracarboxylic bisanhydride

: 56745-93-8,56782-33-3,56782-35-5,56782-36-6,72598-54-0,81203-29-4,108211-26-3,108211-27-4
tetramethyl all-trans-bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / CH(OMe)3; TsOH*H₂O / 120 h / Heating

2: sodium methoxide / methanol / 55 h / Heating

With sodium methylate; toluene-4-sulfonic acid; trimethyl orthoformate; In methanol;
DOI:10.1039/b413082k