Benzene, ((2-phenoxyethyl)thio)-

Base Information

• Chemical Name: Benzene, ((2-phenoxyethyl)thio)-
• CAS No.: 17414-04-9
• Molecular Formula: C14H14 O S
• Molecular Weight: 230.331
• Hs Code.: 2930909090
• Mol file: 17414-04-9.mol

Synonyms:Ether,phenyl 2-(phenylthio)ethyl (6CI,8CI); NSC 115092

Chemical Property of Benzene, ((2-phenoxyethyl)thio)-

Chemical Property:

• Vapor Pressure: 4.83E-05mmHg at 25°C
• Boiling Point: 359.7°Cat760mmHg
• Flash Point: 171.3°C
• PSA: 34.53000
• Density: 1.13g/cm³
• LogP: 3.85770

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, ((2-phenoxyethyl)thio)-

There total 6 articles about Benzene, ((2-phenoxyethyl)thio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

methyl 2-(phenylthio)ethyl carbonate (1391906-40-3) + phenol (108-95-2,27073-41-2) → β-phenyl mercaptoethyl phenolate (17414-04-9)

Guidance literature:

In acetonitrile; at 180 ℃; for 24h; Autoclave;

DOI:10.1002/ejoc.201200321

Reference yield: 16.0%

ethyl 2-(phenylthio)ethyl carbonate (19075-98-0) + phenol (108-95-2,27073-41-2) → β-phenyl mercaptoethyl phenolate (17414-04-9)

Guidance literature:

In acetonitrile; at 180 ℃; for 24h; Autoclave;

DOI:10.1002/ejoc.201200321

Reference yield:

2-phenylethyl chloride (622-24-2) + thiophenol (108-98-5) → β-phenyl mercaptoethyl phenolate (17414-04-9)

Guidance literature:

With sodium hydroxide; In ethanol; for 1h; Heating;

DOI:10.1021/jo01275a030

upstream raw materials:

thiophenol

2-chloroethoxybenzene

2-phenylethyl chloride

2-Chloroethyl phenyl sulfide

Downstream raw materials:

β-Acetoxy-β-phenyl-mercapto-phenetol

Phenyl-<2-phenylmercapto-vinyl>-aether

phenyl(2-ethoxyethyl)sulfoxide

2-ethoxyethyl phenyl sulphone

Refernces

• 1、 Xie, Hai-Qi,Truong, Nguyen,Buncel, Erwin,Purdon, J. Garfield. "Basicity, nucleophilicity, and nucleofugality in the elimination-substitution reactions of β-phenylmercaptoethyl phenolates in DMSO-ethanol media". . p. 448 - 453. Retrieved 2007/10/02.