Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-

Base Information

• Chemical Name: Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-
• CAS No.: 713542-04-2
• Molecular Formula: C₄₈H₃₀
• Molecular Weight: 606.766
• Mol file: 713542-04-2.mol

Synonyms:1,3,5-tri(anthracen-9-yl)benzene;Anthracene,9,9',9''-(1,3,5-benzenetriyl)tris;

Chemical Property of Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-

Chemical Property:

• Melting Point: >300°C
• PSA: 0.00000
• LogP: 13.60680

Purity/Quality:

99% ^*data from raw suppliers

1,3,5-Tri(anthracen-9-yl)benzene(contains~20%inorganics) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1,3,5-Tri(anthracen-9-yl)benzene is a polycyclic aromatic hydrocarbon used in the preparation of porous metal-?organic polyhedral frameworks for methane storage. 1,3,5-Tri(anthracen-9-yl)benzene is used in the preparation of starburst oligofluorenes as deep-blue OLED emitters.

Technology Process of Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris-

There total 6 articles about Anthracene, 9,9',9''-(1,3,5-benzenetriyl)tris- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

9-(ω-nitrovinyl)anthracene (58349-77-2) → 1,3,5-tri(anthracen-9-yl)benzene (713542-04-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 120 ℃; for 0.25h; Sealed tube;

DOI:10.1002/ejoc.201801290

Reference yield: 55.0%

1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) + 2,2’-dibromodiphenylmethane (61592-89-0) → 1,3,5-tri(anthracen-9-yl)benzene (713542-04-2)

Guidance literature:

2,2’-dibromodiphenylmethane; With magnesium; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere; Reflux;

1,3,5-tris-(methoxycarbonyl)benzene; In tetrahydrofuran; at 20 ℃; for 4h; Inert atmosphere;

DOI:10.1002/anie.201505414

Reference yield:

1,3,5-trisbromobenzene (626-39-1) + anthracene-9-boronic acid (100622-34-2) → 1,3,5-tri(anthracen-9-yl)benzene (713542-04-2)

Guidance literature:

1,3,5-trisbromobenzene; anthracene-9-boronic acid; With sodium carbonate; In ethanol; water; toluene; at 80 ℃; for 1h;

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; water; toluene; at 80 ℃; for 4h;

upstream raw materials:

1,3,5-trisbromobenzene

anthracene-9-boronic acid

1,3,5-tris-(methoxycarbonyl)benzene

2,2’-dibromodiphenylmethane