Bicyclo[2.2.1]heptane-2,6-diol, acetate 4-methylbenzenesulfonate, (2-exo,6-endo)-

Base Information

Chemical Name:Bicyclo[2.2.1]heptane-2,6-diol, acetate 4-methylbenzenesulfonate, (2-exo,6-endo)-
CAS No.:72150-05-1
Molecular Formula:C₁₆H₂₀O₅S
Molecular Weight:324.398
Hs Code.:

Synonyms:

Suppliers and Price of Bicyclo[2.2.1]heptane-2,6-diol, acetate 4-methylbenzenesulfonate, (2-exo,6-endo)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[2.2.1]heptane-2,6-diol, acetate 4-methylbenzenesulfonate, (2-exo,6-endo)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Bicyclo[2.2.1]heptane-2,6-diol, acetate 4-methylbenzenesulfonate, (2-exo,6-endo)-

There total 4 articles about Bicyclo[2.2.1]heptane-2,6-diol, acetate 4-methylbenzenesulfonate, (2-exo,6-endo)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 75305-52-1,75364-38-4,78420-72-1,78420-84-5,615249-16-6
Essigsaeur-<6endo-hydroxy-2endo-norbornyl>ester

: 98-59-9
p-toluenesulfonyl chloride

: 72150-05-1,72173-72-9,78420-73-2,78420-81-2
Essigsaeure<6endo-tosyloxy-2endo-norbornyl>ester

Guidance literature:: In pyridine; for 48h; Ambient temperature;
DOI:10.1002/hlca.19820650733

Reference yield:

: 2890-95-1,5257-37-4,6143-29-9,62667-88-3,83679-37-2,99295-40-6,99295-41-7,112836-09-6
5-norbornenyl-2-acetate

: 72150-05-1,72173-72-9,78420-73-2,78420-81-2
Essigsaeure<6endo-tosyloxy-2endo-norbornyl>ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Diboran aus NaBH₄, BF₃*O(C₂H₅)2; 2.) Na₂Cr₂O₇*H₂O 3.) Diboran aus NaBH₄, BF₃*(C₂H₅)2)O / 1.) THF, 0 deg C; 2.) water, ether, 0 deg C; 3.) ether, Rt

2: 92 percent / pyridine / 48 h / Ambient temperature

With sodium dichromate; Diboran aus NaBH₄; boron trifluoride diethyl etherate; In pyridine;
DOI:10.1002/hlca.19820650733

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 72150-05-1,72173-72-9,78420-73-2,78420-81-2
Essigsaeure<6endo-tosyloxy-2endo-norbornyl>ester

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent Chromat_.

2: 1.) Diboran aus NaBH₄, BF₃*O(C₂H₅)2; 2.) Na₂Cr₂O₇*H₂O 3.) Diboran aus NaBH₄, BF₃*(C₂H₅)2)O / 1.) THF, 0 deg C; 2.) water, ether, 0 deg C; 3.) ether, Rt

3: 92 percent / pyridine / 48 h / Ambient temperature

With sodium dichromate; Diboran aus NaBH₄; boron trifluoride diethyl etherate; In pyridine;
DOI:10.1002/hlca.19820650733