(5Z,7E)-5,7-Dodecadien-1-ol

Base Information

• Chemical Name: (5Z,7E)-5,7-Dodecadien-1-ol
• CAS No.: 73416-71-4
• Molecular Formula: C₁₂H₂₂O
• Molecular Weight: 182.306
• Mol file: 73416-71-4.mol

Synonyms:(Z,E)-5,7-dodecadien-1-ol;dodeca-cis-5,trans-7-dien-1-ol;(Z)-5-(E)-7-dodecadien-1-ol;5,7-Dodecadien-1-ol,(E,Z);(5Z,7E)-5,7-dodecadien-1-ol;(Z,E)5,7-dodecadien;5,7-Dodecadien-1-ol,(E,E);5,7-Dodecadien-1-ol,(Z,Z);CIS,TRANS-5,7-DODECADIENOL;

Chemical Property of (5Z,7E)-5,7-Dodecadien-1-ol

Chemical Property:

• PSA: 20.23000
• LogP: 3.45160

Purity/Quality:

99.3% ^*data from raw suppliers

(5Z,7E)-Dodecadien-1-ol(~90%,upto10%of5E,7Eisomer) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: (5Z,7E)-Dodecadien-1-ol is a component of the female sex pheromone of the pine caterpillar moth, Dendrolimus kikuchii Matsumura.

Technology Process of (5Z,7E)-5,7-Dodecadien-1-ol

There total 46 articles about (5Z,7E)-5,7-Dodecadien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.2%

(5Z,7E)-tetrahydro-2-<(5,7-dodecadienyl)-oxy>-2H-pyran (107148-53-8) → (5Z,7E)-5,7-dodecadien-1-ol (73416-71-4,71510-51-5)

Guidance literature:

With pyridinium p-toluenesulfonate; In ethanol; at 55 ℃; for 3h;

DOI:10.1021/ja00241a035

Reference yield: 96.0%

tridec-5t-en-7-yne (65960-08-9) → (5Z,7E)-5,7-dodecadien-1-ol (73416-71-4,71510-51-5)

Guidance literature:

With ethanol; (NCP)IrHCl; tert-butylamine; at 85 ℃; for 24h; stereoselective reaction; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.1c01472

Reference yield: 87.0%

(E)-7-dodecen-5-yn-1-ol (82751-00-6) → (5Z,7E)-5,7-dodecadien-1-ol (73416-71-4,71510-51-5)

Guidance literature:

With water; silver; copper; zinc; In methanol; at 50 - 60 ℃; for 11h;

DOI:10.1021/jf020472s

upstream raw materials:

(E)-2-Heptenal

<5-(acetyloxy)pentyl>triphenylphosphonium bromide

(E)-1-trimethylstannyl-1-hexene

(Z)-6-iodo-5-hexene-1-ol

Downstream raw materials:

(5Z,7E)-5,7-dodecadienal

(5Z,7E)-5,7-dodecadien-1-yl acetate

(5Z,7E)-dodec-5,7-dien-1-yl propionate