Dichlorotris(4-methylphenyl)-lambda~5~-arsane

Base Information

• Chemical Name: Dichlorotris(4-methylphenyl)-lambda~5~-arsane
• CAS No.: 73694-85-6
• Molecular Formula: C21H21AsCl2
• Molecular Weight: 419.225
• DSSTox Substance ID: DTXSID00516237
• Wikidata: Q82377586
• Mol file: 73694-85-6.mol

Synonyms:73694-85-6;Dichlorotris(4-methylphenyl)-lambda~5~-arsane;DTXSID00516237

Chemical Property of Dichlorotris(4-methylphenyl)-lambda~5~-arsane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 418.023626
• Heavy Atom Count: 24
• Complexity: 350

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[As](C2=CC=C(C=C2)C)(C3=CC=C(C=C3)C)(Cl)Cl

Technology Process of Dichlorotris(4-methylphenyl)-lambda~5~-arsane

There total 6 articles about Dichlorotris(4-methylphenyl)-lambda~5~-arsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

tri-p-tolylarsenic phthalimide (86508-93-2) → tri-p-tolylarsenic dichloride (73694-85-6)

Guidance literature:

With tellurium tetrachloride; In benzene; for 3h; Heating;

Reference yield:

tritolylarsine (2896-10-8) → tri-p-tolylarsenic dichloride (73694-85-6)

Guidance literature:

With tetrachloromethane; chlorine;

Reference yield:

tri-p-tolylarsenic dibromide (73694-86-7) → tri-p-tolylarsenic dichloride (73694-85-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / benzene / room temp., 3 h ; reflux, 2 h

2: 62 percent / TeCl₄ / benzene / 3 h / Heating

With tellurium tetrachloride; triethylamine; In benzene;

upstream raw materials:

tritolylarsine

tri-p-tolylarsenic phthalimide

tri-p-tolylarsenic dibromide

oxo-p-tolyl-arsane cyclooligomers

Downstream raw materials:

di-p-tolylarsinous chloride