1-(Diazomethyl)-4-fluorobenzene

Base Information

Chemical Name:1-(Diazomethyl)-4-fluorobenzene
CAS No.:73900-13-7
Molecular Formula:C7H5FN2
Molecular Weight:136.129
Hs Code.:
DSSTox Substance ID:DTXSID80503387
Wikidata:Q82357158

Synonyms:1-(Diazomethyl)-4-fluorobenzene;73900-13-7;SCHEMBL8667204;DTXSID80503387

Suppliers and Price of 1-(Diazomethyl)-4-fluorobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1-(Diazomethyl)-4-fluorobenzene

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:136.04367633
Heavy Atom Count:10
Complexity:144

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=CC=C1C=[N+]=[N-])F

Technology Process of 1-(Diazomethyl)-4-fluorobenzene

There total 3 articles about 1-(Diazomethyl)-4-fluorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 210422-66-5
4-fluorobenzaldehyde p-toluenesulfonylhydrazone

: 73900-13-7
1-(diazomethyl)-4-fluorobenzene

Guidance literature:: 4-fluorobenzaldehyde p-toluenesulfonylhydrazone; With sodium methylate; In methanol;

at 90 - 220 ℃; for 1h; Pyrolysis;
DOI:10.15227/orgsyn.064.0207

Reference yield:

: 459-57-4
4-fluorobenzaldehyde

: 73900-13-7
1-(diazomethyl)-4-fluorobenzene

Guidance literature:: Multi-step reaction with 2 steps

1: methanol / 0.5 h

2: 1.) sodium methoxide / 1.) methanol, 2.) vacuum pyrolysis

With sodium methylate; In methanol;
DOI:10.1021/ja00525a025

Reference yield:

: 401514-49-6
[(4-fluorophenyl)methylidene]hydrazine

: 73900-13-7
1-(diazomethyl)-4-fluorobenzene

Guidance literature:: With manganese(IV) oxide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 0.166667h;
DOI:10.1002/anie.201611067