Benzenesulfinic acid, silver(1+) salt

Base Information

• Chemical Name: Benzenesulfinic acid, silver(1+) salt
• CAS No.: 7449-23-2
• Molecular Formula: C6H6O2S.Ag
• Molecular Weight: 249.039
• Mol file: 7449-23-2.mol

Synonyms:

Chemical Property of Benzenesulfinic acid, silver(1+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenesulfinic acid, silver(1+) salt

There total 3 articles about Benzenesulfinic acid, silver(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

benzenesulfinic acid sodium dihydrate (25932-11-0) + silver nitrate → silver (I) phenyl sulfinate (7449-23-2)

Guidance literature:

In ethanol; water; N2-atmosphere; treatment of NaSO2Ph (in EtOH) with equimolar amt. of aq.AgNO3 (pptn.); filtration, washing (water, Me2CO), drying (reduced pressure, over P2O5); elem. anal.;

DOI:10.1039/DT9770000578

Reference yield:

sodium benzenesulfonate (873-55-2) → silver (I) phenyl sulfinate (7449-23-2)

Guidance literature:

With silver nitrate; In water;

DOI:10.1021/acs.joc.6b02416

Reference yield:

2Ag(1+)*C6H5NO3S(2-)={Ag2C6H5NO3S} → silver (7440-22-4) + silver (I) phenyl sulfinate (7449-23-2)

Guidance literature:

byproducts: NO;

upstream raw materials:

benzenesulfinic acid sodium dihydrate

sodium benzenesulfonate

Downstream raw materials:

Triphenylsiliziumbenzolsulfinsaeureester

Tris-(benzolsulfinato-O)-phenylsilizium

(ethanesulphinato)(tricyclohexylphosphine)gold(I)

(benzenesulphinato)(tricyclohexylphosphine)gold(I)

Refernces