Tridecanoic acid, 3-oxo-, ethyl ester

Base Information

• Chemical Name: Tridecanoic acid, 3-oxo-, ethyl ester
• CAS No.: 74631-91-7
• Molecular Formula: C15H28O3
• Molecular Weight: 256.386
• Mol file: 74631-91-7.mol

Synonyms:

Chemical Property of Tridecanoic acid, 3-oxo-, ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tridecanoic acid, 3-oxo-, ethyl ester

There total 1 articles about Tridecanoic acid, 3-oxo-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

undecanoyl chloride (17746-05-3) → dodecan-2-one (6175-49-1) + ethyl 3-oxotridecanoate (74631-91-7)

Guidance literature:

Erwaermen des nach dem Ansaeuern erhaltenen Reaktionsprodukts mit Essigsaeure und wenig Schwefelsaeure;

Reference yield:

ethyl 3-oxotridecanoate (74631-91-7) → dodecan-2-one (6175-49-1)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In xylene; for 5h; Heating;

DOI:10.1021/jm00072a014

Reference yield:

ethyl 3-oxotridecanoate (74631-91-7) → N-[2,6-bis(1-methylethyl)phenyl]-3-oxotridecanamide

Guidance literature:

Multi-step reaction with 2 steps

1: 1,4-diazabicyclo<2.2.2>octane (DABCO) / xylene / 5 h / Heating

2: 1.) LDA / 1.) ether, -78 deg C, 20 min, 2.) ether, from -78 deg C to RT, 16 h

With 1,4-diaza-bicyclo[2.2.2]octane; lithium diisopropyl amide; In xylene;

DOI:10.1021/jm00072a014

upstream raw materials:

undecanoyl chloride

Downstream raw materials:

3-hydroxytridecanoic acid ethyl ester

dodecan-2-one