Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)-

Base Information

Chemical Name:Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)-
CAS No.:748788-76-3
Molecular Formula:C18H19NO3
Molecular Weight:297.354
Hs Code.:
DSSTox Substance ID:DTXSID00470648
Wikidata:Q82298804

Synonyms:748788-76-3;Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)-;DTXSID00470648

Suppliers and Price of Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)-

Chemical Property:

XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:297.13649347
Heavy Atom Count:22
Complexity:417

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(=O)C(C1)C(C[N+](=O)[O-])C2=CC3=CC=CC=C3C=C2
Isomeric SMILES:C1CCC(=O)[C@@H](C1)[C@@H](C[N+](=O)[O-])C2=CC3=CC=CC=C3C=C2

Technology Process of Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)-

There total 16 articles about Cyclohexanone, 2-[(1R)-1-(2-naphthalenyl)-2-nitroethyl]-, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 37629-37-1,21461-46-1
2-(2-nitrovinyl)naphthalene

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 748788-76-3
(S)-2-((R)-1-naphthalen-2-yl-2-nitro-ethyl)-cyclohexanone

Guidance literature:: With C₁₁₉H₁₀₈N₄O₁₅; trifluoroacetic acid; at 20 ℃; for 18h; optical yield given as %ee;
DOI:10.1016/j.tetasy.2008.10.016

Reference yield: 90.0%

: 21461-46-1,37629-37-1
(E)-2-(2-nitrovinyl)naphthalene

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 2-(1-naphthalen-2-yl-2-nitro-ethyl)-cyclohexanone

: 748788-76-3
(S)-2-((R)-1-naphthalen-2-yl-2-nitro-ethyl)-cyclohexanone

Guidance literature:: N¹,N¹-dimethyl-N²-(((S)-pyrrolidin-2-yl)methyl)ethane-1,2-diamine; toluene-4-sulfonic acid; In N,N-dimethyl-formamide; at 20 ℃; for 24h;
DOI:10.1021/ja062701n

Reference yield:

: 21461-46-1,37629-37-1
(E)-2-(2-nitrovinyl)naphthalene

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 748788-76-3
(S)-2-((R)-1-naphthalen-2-yl-2-nitro-ethyl)-cyclohexanone

: (2R,1'S)-2-(1-(naphthalen-2-yl)-2-nitroethyl)cyclohexan-1-one

Guidance literature:: With 2,4-dinitrobenzenesulfonic acid hydrate; (S)-4-dimethylamino-2-(pyrrolidin-2-yl-methyl)pyridine; In chloroform; at 0 ℃; for 24h; Title compound not separated from byproducts;
DOI:10.1021/ja046871g