Technology Process of (5E,7Z)-5,7-Dodecadienal
There total 18 articles about (5E,7Z)-5,7-Dodecadienal which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
Pyr*CrO3*HCl;
In
dichloromethane;
at 10 - 20 ℃;
for 3h;
DOI:10.1007/BF02234863
- Guidance literature:
-
With
sulfuric acid;
In
methanol;
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: HMDS-Na / tetrahydrofuran / 0.5 h / -20 °C
1.2: 3.8 g / tetrahydrofuran / 13 h / -78 - 20 °C
2.1: 96 percent / LiAlH4 / diethyl ether / 3 h / -10 - 20 °C
3.1: 2.1 g / Py*CrO3*HCl / CH2Cl2 / 3 h / 20 °C
4.1: HMDS-Na / tetrahydrofuran / -20 °C
4.2: 1.5 g / tetrahydrofuran / 13 h / -70 - 20 °C
5.1: 9-BBN / tetrahydrofuran / 2 h
5.2: 60 percent / aq. NaOH; H2O2 / H2O; tetrahydrofuran / 2 h / 25 °C
6.1: 84.2 percent / Py*CrO3*HCl / CH2Cl2 / 3 h / 10 - 20 °C
With
lithium aluminium tetrahydride; 9-borabicyclo[3.3.1]nonane dimer; Pyr*CrO3*HCl; sodium hexamethyldisilazane;
In
tetrahydrofuran; diethyl ether; dichloromethane;
1.1: Dehydrobromination / 1.2: Wittig reaction / 2.1: Reduction / 3.1: Oxidation / 4.1: Elimination / 4.2: Wittig reaction / 5.1: hydroboration / 5.2: Oxidation / 6.1: Oxidation;
DOI:10.1007/BF02234863