Technology Process of Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-butenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-
There total 6 articles about Silane, (1,1-dimethylethyl)dimethyl((2-(2-methyl-2-butenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 80 percent / TEA, DMAP / tetrahydrofuran; dimethylformamide / Heating
2: 1.) O3, 2.) Me2S / 1.) MeOH, - 60 deg C
3: 1.) NaH / 1.) THF
4: 54 percent / dibal / diethyl ether / -78 - 0 °C
5: 1.) Pyr-SO3, 2.) LiAlH4 / 1.) THF
With
dmap; lithium aluminium tetrahydride; dimethylsulfide; TEA; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; ozone;
In
tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00362a014
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 1.) CuI / 1.) Et2O
2: 80 percent / TEA, DMAP / tetrahydrofuran; dimethylformamide / Heating
3: 1.) O3, 2.) Me2S / 1.) MeOH, - 60 deg C
4: 1.) NaH / 1.) THF
5: 54 percent / dibal / diethyl ether / -78 - 0 °C
6: 1.) Pyr-SO3, 2.) LiAlH4 / 1.) THF
With
dmap; copper(l) iodide; lithium aluminium tetrahydride; dimethylsulfide; TEA; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; ozone;
In
tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00362a014
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) O3, 2.) Me2S / 1.) MeOH, - 60 deg C
2: 1.) NaH / 1.) THF
3: 54 percent / dibal / diethyl ether / -78 - 0 °C
4: 1.) Pyr-SO3, 2.) LiAlH4 / 1.) THF
With
lithium aluminium tetrahydride; dimethylsulfide; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; ozone;
In
diethyl ether;
DOI:10.1021/jo00362a014
