5-Acetoxy-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-1H-cyclopropa[3,4]cycloocta[1,2-c]furan-1-one

Base Information

• Chemical Name: 5-Acetoxy-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-1H-cyclopropa[3,4]cycloocta[1,2-c]furan-1-one
• CAS No.: 65043-52-9
• Molecular Formula: C₂₂H₃₂O₄
• Molecular Weight: 360.494

Synonyms:1H-Cyclopropa[3,4]cycloocta[1,2-c]furan-1-one,5-(acetyloxy)-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-,[4S-[4a(S*),5a,7b,7ab,8ab]]-; (+)-Acetoxycrenulide; Acetoxycrenulatin;Acetoxycrenulide

Chemical Property of 5-Acetoxy-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-1H-cyclopropa[3,4]cycloocta[1,2-c]furan-1-one

Chemical Property:

• PSA: 52.60000
• LogP: 4.44610

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-Acetoxy-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-1H-cyclopropa[3,4]cycloocta[1,2-c]furan-1-one

There total 5 articles about 5-Acetoxy-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-1H-cyclopropa[3,4]cycloocta[1,2-c]furan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Hydroxy-9-acetoxycrenulide (85443-37-4) → Acetoxycrenulide (65043-52-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; for 1.33333h; Ambient temperature;

DOI:10.1021/jo00159a026

Reference yield:

1,9-Dihydroxycrenulide (85443-36-3) → Acetoxycrenulide (65043-52-9)

Guidance literature:

Multi-step reaction with 2 steps

1: NaBH₄ / ethanol / 1.33 h / Ambient temperature

2: Pyridine / 17 h / Ambient temperature

With pyridine; sodium tetrahydroborate; In ethanol;

DOI:10.1021/jo00159a026

Reference yield:

Acetic acid (Z)-(1S,2R,4R,5S,8S)-5-(1,5-dimethyl-hex-4-enyl)-6,7-bis-hydroxymethyl-2-methyl-bicyclo[6.1.0]non-6-en-4-yl ester (118197-33-4) → acetoxycrenulide (65043-52-9)

Guidance literature:

With manganese(IV) oxide; In hexane; Ambient temperature;

DOI:10.1139/v88-432

upstream raw materials:

acetic anhydride

9-Hydroxycrenulide

1-Hydroxy-9-acetoxycrenulide

1,9-Dihydroxycrenulide

Downstream raw materials:

9-Hydroxycrenulide

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 65043-52-9 5-Acetoxy-4-(1,5-dimethyl-4-hexenyl)-3,4,5,6,7,7a,8,8a-octahydro-7-methyl-1H-cyclopropa[3,4]cycloocta[1,2-c]furan-1-one

Send

Send

Metric Ton KG G Pound L ML

Send

Send