(2E)-3,7-dimethylocta-2,6-dien-1-amine

Base Information

• Chemical Name: (2E)-3,7-dimethylocta-2,6-dien-1-amine
• CAS No.: 6246-48-6
• Molecular Formula: C₁₀H₁₉N
• Molecular Weight: 153.268
• European Community (EC) Number: 700-035-8,252-482-9
• DSSTox Substance ID: DTXSID601317828
• Nikkaji Number: J37.638H,J260.568F
• Mol file: 6246-48-6.mol

Synonyms:decaprenylamine

Chemical Property of (2E)-3,7-dimethylocta-2,6-dien-1-amine

Chemical Property:

• Refractive Index: n20/D 1.476(lit.)
• Boiling Point: 105 °C19 mm Hg(lit.)
• PKA: 9.66±0.29(Predicted)
• Flash Point: 190 °F
• PSA: 26.02000
• Density: 0.829 g/mL at 25 °C(lit.)
• LogP: 3.33810
• Storage Temp.: 2-8°C
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 153.151749610
• Heavy Atom Count: 11
• Complexity: 150

Purity/Quality:

99.9% ^*data from raw suppliers

Geranylamine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=CCCC(=CCN)C)C
• Isomeric SMILES: CC(=CCC/C(=C/CN)/C)C
• Uses: Geranylamine may be employed as starting reagent for the total synthesis of a naturally occurring guanidine alkaloid, Nitensidine D. It may be used for the synthesis of 5-alkylamino- and 2,5-bis(alkylamino)-[1,4]-benzoquinone.

Technology Process of (2E)-3,7-dimethylocta-2,6-dien-1-amine

There total 17 articles about (2E)-3,7-dimethylocta-2,6-dien-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(E)-2‐(3,7‐dimethylocta‐2,6‐dien‐1‐yl)isoindoline‐1,3‐dione (36615-20-0) → geranylamine (6246-48-6,35278-77-4,36615-19-7)

Guidance literature:

With hydrazine hydrate; In ethanol; for 8h; Reflux;

DOI:10.1007/s12039-014-0723-8

Reference yield: 92.0%

N-geranyl-3,3-dimethoxypropylsulfonamide → geranylamine (6246-48-6,35278-77-4,36615-19-7)

Guidance literature:

N-geranyl-3,3-dimethoxypropylsulfonamide; With p-toluenesulfonic acid monohydrate; In water; acetone; at 0 - 20 ℃; for 6h;

With sodium hydroxide; In methanol; water; acetone; at 0 - 20 ℃; for 1.08333h;

DOI:10.1016/j.tet.2018.04.088

Reference yield: 50.0%

(E)-1-azido-3,7-dimethylocta-2,6-diene (84457-88-5) → geranylamine (6246-48-6,35278-77-4,36615-19-7)

Guidance literature:

5% Pd/CaCO3; In ethanol; for 12h;

upstream raw materials:

geranial oxime

3,7-dimethyl-2E,6-octadien-1-yl acetate

(E)-1-azido-3,7-dimethylocta-2,6-diene

1-geranylazacyclopentan-2,5-dione

Downstream raw materials:

(E)-3,7-dimethylocta-2,6-dienenitrile

(E)-N-(3,7-dimethylocta-2,6-dienyl)aniline

C₂₃H₃₂NO₃P