3-CARBOXYPHENYLPHOSPHONIC ACID

Base Information

• Chemical Name: 3-CARBOXYPHENYLPHOSPHONIC ACID
• CAS No.: 14899-31-1
• Molecular Formula: C7H7 O5 P
• Molecular Weight: 202.103
• Hs Code.: 2931900090
• Mol file: 14899-31-1.mol

Synonyms:(m-Carboxyphenyl)phosphonicacid; 3-Phosphonobenzoic acid; NSC 408732; NSC 666474

Chemical Property of 3-CARBOXYPHENYLPHOSPHONIC ACID

Chemical Property:

• Vapor Pressure: 1.46E-11mmHg at 25°C
• Melting Point: 256 °C
• Boiling Point: 518.1°Cat760mmHg
• PKA: 1.58±0.10(Predicted)
• Flash Point: 267.2°C
• PSA: 104.64000
• Density: 1.65g/cm³
• LogP: 0.18780
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: Methanol (Slightly), Water (Slightly)

Purity/Quality:

97% ^*data from raw suppliers

3-Phosphonobenzoic Acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-CARBOXYPHENYLPHOSPHONIC ACID

There total 8 articles about 3-CARBOXYPHENYLPHOSPHONIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

meta-aminobenzoic acid (99-05-8,159139-79-4) → 3-carboxyphenylphosphonic acid (14899-31-1)

Guidance literature:

With phosphorus trichloride; Diazotization_.anschliessend mit H₂O;

DOI:10.1021/ja01105a054

Reference yield:

m-tolylphosphonic acid (77918-48-0) → 3-carboxyphenylphosphonic acid (14899-31-1)

Guidance literature:

With potash permanganate; water; potassium carbonate; at 50 ℃;

Reference yield:

diethyl (3-methoxycarbonyl)phenylphosphonate (107658-35-5) → 3-carboxyphenylphosphonic acid (14899-31-1)

Guidance literature:

With hydrogenchloride; Yield given; Heating;

upstream raw materials:

m-tolylphosphonic acid

meta-aminobenzoic acid

diethyl (3-methoxycarbonyl)phenylphosphonate

methyl 3-iodo-benzoate

Downstream raw materials:

diethyl 3-(ethoxycarbonyl)phenylphosphonate

[Mn(water)(3-phosphonobenzoic acid(-2H))]

[Co(water)(3-phosphonobenzoic acid(-2H))]

[Zn(water)(3-phosphonobenzoic acid(-2H))]