(3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate

Base Information

Chemical Name:(3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate
CAS No.:97042-20-1
Molecular Formula:C₂₄H₃₆O₆
Molecular Weight:420.546
Hs Code.:
Mol file:97042-20-1.mol

(3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate

Synonyms:

Suppliers and Price of (3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate

Chemical Property:

PSA：82.06000
LogP:3.79490

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate

There total 4 articles about (3R,3aα,5aα,9aβ,11aα,12R)-3β,3bβ-(Epoxymethano)-4α,12-dihydroxy-3a,3b,4,5,5a,6,7,8,9,9a,9bα,10,11,11a-tetradecahydro-6,6,9a-trimethylphenanthro[1,2-c]furan-1(3H)-one 4-butyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (4aS,4bR,7aR,9aS,10R,11aS)-10-Hydroxy-1,1,4a-trimethyl-1,3,4,4a,4b,5,6,7,7a,10,11,11a-dodecahydro-2H-cyclobuta[j]phenanthrene-7-carboxylic acid

: 97042-20-1
aplyroseol-1

Guidance literature:: Multi-step reaction with 4 steps

1: diethyl ether

2: 89 percent / 4-pyrrolidinopyridine, triethylamine / 0.75 h / 0 °C

3: 84 percent / aq. KOH / methanol / 15 h / Ambient temperature

4: 1.) ozone, 2.) Me₂S / 1) CH₂Cl₂, -78 deg C, few min; 2) CH₂Cl₂, RT, 18 h

With potassium hydroxide; dimethylsulfide; 4-pyrrolidin-1-ylpyridine; ozone; triethylamine; In methanol; diethyl ether;

Reference yield:

: 152715-34-9
<3R-(3aα,5aS,7aα,11aβ,11bα)>-(-)-methyl 6α-butyroxy-1,3,3a,6,7,7a,8,9,10,11,11a,11b-dodecahydro-8,8,11a-trimethyl-2H-cyclobuta-phenanthrene-3β-carboxylate

: 97042-20-1
aplyroseol-1

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / aq. KOH / methanol / 15 h / Ambient temperature

2: 1.) ozone, 2.) Me₂S / 1) CH₂Cl₂, -78 deg C, few min; 2) CH₂Cl₂, RT, 18 h

With potassium hydroxide; dimethylsulfide; ozone; In methanol;

Reference yield:

: 152715-31-6
<3R-(3aα,5aS,7aα,11aβ,11bα)>-(+)-methyl 1,3,3a,6,7,7a,8,9,10,11,11a,11b-dodecahydro-6α-hydroxy-8,8,11a-trimethyl-2H-cyclobuta-phenanthrene-3β-carboxylate

: 97042-20-1
aplyroseol-1

Guidance literature:: Multi-step reaction with 3 steps

1: 89 percent / 4-pyrrolidinopyridine, triethylamine / 0.75 h / 0 °C

2: 84 percent / aq. KOH / methanol / 15 h / Ambient temperature

3: 1.) ozone, 2.) Me₂S / 1) CH₂Cl₂, -78 deg C, few min; 2) CH₂Cl₂, RT, 18 h

With potassium hydroxide; dimethylsulfide; 4-pyrrolidin-1-ylpyridine; ozone; triethylamine; In methanol;