Benzonitrile, 3-(tributylstannyl)-

Base Information

Chemical Name:Benzonitrile, 3-(tributylstannyl)-
CAS No.:79062-29-6
Molecular Formula:C19H31NSn
Molecular Weight:392.172
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzonitrile, 3-(tributylstannyl)-

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Technology Process of Benzonitrile, 3-(tributylstannyl)-

There total 4 articles about Benzonitrile, 3-(tributylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 6952-59-6
3-cyanobromobenzene

: 1461-22-9
tributyltin chloride

: 79062-29-6
3-(tributylstannyl)benzonitrile

Guidance literature:: With n-butyllithium; In hexane; tetrahydrofuran; n-butyllithium in hexane added dropwise to THF soln. of ligand, stirred for 1 min, stirred for 10 min, soln. of MeOH in THF added, stirred for 10 min, Sn-compound in THF added at 0°C in microflow system, quenched with H2O; extd., silica gel column chromy. with hexane-AcOEt 20:1;
DOI:10.1039/b919325c

Reference yield: 60.0%

: 17955-46-3
trimethylsilyltributyltin

: 180143-66-2
2,2-Dimethyl-propionic acid 3-cyano-phenyl ester

: 79062-29-6
3-(tributylstannyl)benzonitrile

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; cesium fluoride; 1,2-bis-(dicyclohexylphosphino)ethane; In toluene; at 90 ℃; for 8h; Inert atmosphere; Sealed tube;
DOI:10.1002/anie.201611720

Reference yield: 31.0%

: 6952-59-6
3-cyanobromobenzene

: 813-19-4
bis(tri-n-butyltin)

: 79062-29-6
3-(tributylstannyl)benzonitrile

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; byproducts: Bu3SnBr, m,m'-di-CN-biphenyl; heating at 80°C with stirring under Ar atm., reaction completed when color of the soln. changed to black; solvent evapd., biaryl filtered off after recrystn., filtrate washed with aq. KF, organic layer extd. with benzene, dried over sodium sulfate, product chromd.;