6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

Base Information

Chemical Name:6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine
CAS No.:79440-34-9
Molecular Formula:C9H9BrO2
Molecular Weight:229.073
Hs Code.:2932999099
European Community (EC) Number:806-353-4
DSSTox Substance ID:DTXSID40455459
Wikidata:Q82277489
Mol file:79440-34-9.mol

Synonyms:6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine;79440-34-9;6-Bromomethyl-2,3-dihydro-benzo[1,4]dioxine;6-(BROMOMETHYL)-2,3-DIHYDRO-1,4-BENZODIOXINE;1,4-Benzodioxin, 6-(bromomethyl)-2,3-dihydro-;SCHEMBL1743000;DTXSID40455459;DQYOHFCVPNOXQQ-UHFFFAOYSA-N;AKOS009317462;AM101294;E85060;6-(Bromomethyl)-2,3-dihydro-benzo[1,4]dioxine;EN300-1252135;A864861;J-518048

Suppliers and Price of 6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine
5g
$ 4410.00

Matrix Scientific
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine
1g
$ 1470.00

Matrix Scientific
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine
250mg
$ 488.00

Crysdot
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine 95+%
250mg
$ 720.00

Crysdot
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine 95+%
1g
$ 1455.00

Chemenu
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine 95%
1g
$ 729.00

American Custom Chemicals Corporation
6-(BROMOMETHYL)-2,3-DIHYDROBENZO[B][1,4]DIOXINE 95.00%
2G
$ 1674.75

Alichem
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine
1g
$ 634.28

Alichem
6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine
250mg
$ 305.76

Total 10 raw suppliers

Chemical Property of 6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

Chemical Property:

Boiling Point:291.2±19.0 °C(Predicted)
PSA：18.46000
Density:1.549±0.06 g/cm3(Predicted)
LogP:2.35270
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:227.97859
Heavy Atom Count:12
Complexity:152

Purity/Quality:

97% ^*data from raw suppliers

6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi,N
Statements: 36-51/53
Safety Statements: 26-60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COC2=C(O1)C=CC(=C2)CBr

Technology Process of 6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

There total 5 articles about 6-(Bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 39270-39-8
(2,3-dihydro-benzo[1,4]dioxin-6-yl)-methanol

: 79440-34-9
6-(bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

Guidance literature:: With phosphorus tribromide; In dichloromethane; at 0 ℃; for 0.5h;

Reference yield:

: 29668-44-8
2,3-dihydro-benzo[1,4]dioxin-6-carbaldehyde

: 79440-34-9
6-(bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / dichloromethane / 0.5 h / 20 °C

2: phosphorus tribromide / dichloromethane / 0.5 h / 0 °C

With sodium tetrahydroborate; phosphorus tribromide; In dichloromethane;
DOI:10.1016/j.ejmech.2012.07.010

Reference yield:

: 4442-54-0
2,3-dihydro-1,4-benzodioxin-6-carboxylic acid

: 79440-34-9
6-(bromomethyl)-2,3-dihydrobenzo[b][1,4]dioxine

Guidance literature:: Multi-step reaction with 2 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / -10 - 20 °C / Inert atmosphere

2: phosphorus tribromide / dichloromethane / 2 h / 0 °C

With lithium aluminium tetrahydride; phosphorus tribromide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jm1008902