2-[(Trimethylsilyl)methyl]prop-2-en-1-ol

Base Information

• Chemical Name: 2-[(Trimethylsilyl)methyl]prop-2-en-1-ol
• CAS No.: 81302-80-9
• Molecular Formula: C7H16OSi
• Molecular Weight: 144.289
• DSSTox Substance ID: DTXSID10444931
• Nikkaji Number: J582.181I
• Wikidata: Q82263213
• Mol file: 81302-80-9.mol

Synonyms:81302-80-9;2-(trimethylsilylmethyl)prop-2-en-1-ol;2-[(Trimethylsilyl)methyl]prop-2-en-1-ol;2-Propen-1-ol, 2-[(trimethylsilyl)methyl]-;SCHEMBL4385406;DTXSID10444931;2-(Trimethylsilylmethyl)-2-propene-1-ol;2-[(trimethylsilyl)methyl]-2-propen-1-ol;BB 0262942

Chemical Property of 2-[(Trimethylsilyl)methyl]prop-2-en-1-ol

Chemical Property:

• PSA: 20.23000
• LogP: 1.87310
• Solubility.: Insol water; sol all organic liquids.
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 144.097041664
• Heavy Atom Count: 9
• Complexity: 102

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)CC(=C)CO
• Physical properties: bp 54–56 °C/2 mmHg; nD 20 1.454; d 0.861 g cm?3; fp 71?C.
• Uses: 2-Trimethylsilylmethyl-2-propen-1-ol reagent has been employed as a conjunctive reagent which is considered to be a synthetic equivalent of a zwitterionic, bifunctional compound possessing a nucleophilic allylic anion synthon and an electrophilic cation synthon in the same molecule. Derivatives function as trimethylenemethane (TMM) precursors and undergo cyclopentannulation reactions; methylenecyclopentanes; 2-acetoxymethyl-3-trimethylsilylpropene; [3+2] annulation; Methylenecyclopentane Annulation,Cyclocontraction-Spiroannulation, three-carbon condensative expansion; cyclocontraction–spiroannulation.